NMR Methods

Deterministic schedules for robust and reproducible non-uniform sampling in multidimensional NMR. Eddy MT, Ruben D, Griffin RG and Herzfeld J. J Magn Res 214, 296-301 (2012). Abstract

Rapid 3D MAS NMR at Critical Sensitivity. Matsuki Y, Eddy MT, Griffin RG and Herzfeld J. Angewandte Chemie Int Ed 49, 9215-9218 (2010).

Resolution and Polarization Distribution in Cryogenic DNP/MAS Experiments. Barnes AB, Corzilius B, Mak-Jurkauskas ML, Andreas LB, Bajaj VJ, Matsuki Y, Belenky MB, Lugtenburg J, Sirigi JR, Temkin RJ, Herzfeld J, and Griffin RG. Phys Chem Chem Phys 12, 5861-5867 (2010). Abstract

Cryogenic sample exchange NMR probe for magic angle spinning dynamic nuclear polarization. Barnes AB, Mak-Jurkauskas ML, Matsuki Y, Bajaj VS, van der Wel PC, Derocher R, Bryant J, Sirigiri JR, Temkin RJ, Lugtenburg J, Herzfeld J, Griffin RG. J Magn Res 198, 261-270 (2009). Abstract

DNP enhanced frequency-selective TEDOR experiments in bacteriorhodopsin. Bajaj VJ, Mak-Jurkauskas ML, Belenky MB, Herzfeld J, and Griffin RG. J Magn Res 202, 9-13 (2009). Abstract

Dynamic Nuclear Polarization using a Rigid Biradical. Matsuki Y, Maly T, Olivier Ouari O, Lyubenova S, Herzfeld J, Prisner T, Tordo P and Griffin RG. Angewandte Chemie Int Ed 48, 4996-5000 (2009). Abstract

Spectroscopy by integration of frequency and time domain information for fast acquisition of high-resolution dark spectra. Matsuki Y, Eddy MT, Herzfeld J. J Am Chem Soc 131, 4648-4656 (2009). Abstract
High-Field Dynamic Nuclear Polarization for Solid and Solution Biological NMR. Barnes AB, Pa‘pe GD, van der Wel PC, Hu KN, Joo CG, Bajaj VS, Mak-Jurkauskas ML, Sirigiri JR, Herzfeld J, Temkin RJ, Griffin R Appl Magn Reson 34, 237-263 (2009). Abstract

Dynamic nuclear polarization at high magnetic fields. Maly T, Debelouchina GT, Bajaj VS, Hu KN, Joo CG, Mak-Jurkauskas ML, Sirigiri JR, van der Wel PC, Herzfeld J, Temkin RJ, Griffin RG. J Chem Phys 128, 052211 (2008). Abstract

250 GHz CW Gyrotron Oscillator for Dynamic Nuclear Polarization in Biological Solid State NMR. Bajaj VS, Hornstein MK, Kreischer KE, Sirigiri JR, Woskov P, Mak-Jurkauskas ML, Herzfeld J, Temkin RJ, Griffin RG. J Magn Reson 189, 251-279 (2007). Abstract

High-Frequency Dynamic Nuclear Polarization in MAS Spectra of Membrane and Soluble Proteins. Rosay M, Lansing JC, Haddad KC, Bachovchin WW, Herzfeld J, Temkin RJ, and Griffin RG. J Am Chem Soc 125, 13626-13627 (2003). Abstract PDF

Backbone and Sidechain Assignment Strategies for Multiply Labeled Membrane Peptides and Proteins. Petkova AT, Baldus M, Belenky M, Hong M, Herzfeld J and Griffin RG. J. Magn. Reson. 160, 1-12 (2003). Abstract PDF

Measurement of Dipolar Couplings in a Uniformly ¹³C-¹⁵N -Labeled Membrane Protein: Distances between the Schiff Base and Aspartic Acids in the Active Site of Bacteriorhodopsin. Jaroniec CP, Lansing JC, Tounge BA, Belenky M, Herzfeld J and Griffin RG. J. Am. Chem. Soc. 123 12929-12930 (2001). PDF

Frequency Selective Heteronuclear Dipolar Recoupling in Rotating Solids: Accurate 13C-15N Distance Measurements in Uniformly-13C,15N-labeled Peptides. Jaroniec CP, Tounge BA, Herzfeld J and Griffin RG. J Am Chem Soc 123, 3507-3519 (2001). Abstract PDF

Sensitivity-Enhanced NMR of Biological Solids: Dynamic Nuclear Polarization of Y21M fd Bacteriophage and Purple Membrane. Rosay M, Zeri AC, Astrof NS, Opella SJ, Herzfeld J and Griffin RG. J. Am. Chem. Soc. 123, 1010-1011 (2001). PDF

Structural decomposition of the chemical shielding tensor: Contributions to the asymmetry, anisotropy, and orientation. Herzfeld J, Olbris DJ, Furman E, and Benderskiy V. J. Chem. Phys. 113, 5162-5170 (2000). Abstract PDF

Measurement of ¹³C-¹⁵N Distances in Uniformly ¹³C Labeled Biomolecules: J-Decoupled REDOR. Jaroniec CP, Tounge BA, Rienstra CM, Herzfeld J, and Griffin RG. J. Am. Chem. Soc. 121, 10237-10238 (1999). PDF

Cross polarization in the tilted frame: assignment and spectral simplification in heteronuclear spin systems. Baldus M, Petkova AT, Herzfeld J, and Griffin RG. Mol. Phys. 95, 1197-1207 (1998). Abstract

Bacteriorhodopsin and Rhodopsin. Herzfeld J and Hu JG. Encyclopedia of NMR, pp.862-871, Wiley (Chichester, 1996).

Sideband Analysis in Magic Angle Spinning Solids. Herzfeld J and Chen X. Encyclopedia of NMR, pp. 4362-4369, Wiley (Chichester, 1996).

Dipolar Correlation NMR Spectroscopy of a Membrane Protein. Griffiths JM, Lakshmi KV, Bennett AE, Raap J, van der Wielen CM, Lugtenburg J, Herzfeld J and Griffin RG. J Am Chem Soc 116, 10178-10181 (1994). PDF

Rotational Resonance NMR Studies of Membrane Protein Structure: Bacteriorhodopsin. Creuzet F, McDermott A, Gebhardt R, van der Hoef K, Spijker-Assink MB, Herzfeld J, Lugtenburg J, Levitt MH and Griffin RG. Science 251, 783-786 (1991). Abstract

Iterative Fitting of Magic Angle Spinning NMR Spectra. de Groot HJM, Smith SO, Kolbert AC, Courtin JML, Winkel C. Lugtenburg J, Griffin RG and Herzfeld J. J Mag Res 91, 30-38 (1990).

Magic-Angle-Sample-Spinning NMR Difference Spectroscopy. de Groot HJM, Copie V, Smith SO, Allen PJ, Winkel C, Lugtenburg J, Herzfeld J and Griffin RG. J Mag Res 77, 251-257 (1988).

Measurement of Heteronuclear Bond Distances in Polycrystalline Solids by Solid-State NMR Techniques. Roberts JE, Harbison GS, Munowitz MG, Herzfeld J and Griffin RG. J Am Chem Soc 109, 4163-4169 (1987). PDF

Sideband Intensities in Two Dimensional NMR Spectra of Rotating Solids. Herzfeld J, Roberts JE and Griffin RG. J Chem Phys 86, 597-602 (1987). Abstract PDF

High-Field 2D Exchange Spectroscopy in Rotating Solids. Harbison GS, Raleigh DP, Herzfeld J and Griffin RG. J Mag Res 64, 284-295 (1985).

Diagonal Peak Suppression in 2D-NOE Spectra. Harbison GS, Feigon J, Ruben DJ, Herzfeld J and Griffin RG. J Am Chem Soc 107, 5567-5569 (1985). PDF

NMR Structural Analysis of a Membrane Protein: Bacteriorhodopsin Peptide Backbone Orientation and Motion. Lewis BA, Harbison GS, Herzfeld J and Griffin RG. Biochemistry 24, 4671-4679 (1985). Abstract

Sideband Intensities in NMR Spectra of Samples Spinning at the Magic Angle. Herzfeld J and Berger AE. J Chem Phys 73, 6021-6030 (1980). Abstract PDF

High Resolution ³¹P and ¹³C Nuclear Magnetic Resonance Spectra of Unsonicated Model Membranes. Haberkorn RA, Herzfeld J and Griffin RG. J Am Chem Soc 100, 1296-1298 (1978). PDF