Publications

Ozerov group publications

(31) Ozerov, O. V., "Oxidative Addition of Water to Transition Metal Complexes", Chem. Soc. Rev. 2009, in press, DOI:10.1039/B802420K.

(30) Sircoglou, M.; Bontemps, S.; Bouhadir, G.; Saffon, N.; Miqueu, K.; Gu, W.; Mercy, M.; Chen, C.-H.; Foxman, B.; Maron, L.; Ozerov, O. V.; Bourissou, D. "Group 10 and 11 Metal Boratranes (Ni, Pd, Pt, CuCl, AgCl, AuCl and Au+) Derived from a Triphosphine–Borane", J. Am. Chem. Soc., in press.

(29) Gatard,^P S.; Chen, C.-H.; Foxman, B. M.; Ozerov, O. V. "Oxidative Addition Reactions of Silyl Halides with the (PNP)Rh fragment", Organometallics, in press.

(28) Douvris,^P C.; Ozerov, O. V. "Hydrodefluorination of Perfluoroalkyl Groups Using Silylium-Carborane Catalysts", Science 2008, 321, 1188. Please see the press coverage summary here.

(27) Masuda, J. D.; Jantunen, K. C.; Ozerov, O. V.; Noonan, K. J. T.; Gates, D. P.; Scott, B. L.; Kiplinger, J. L. "A Lanthanide Phosphinidene Complex: Synthesis, Structure, and Phospha-Wittig Reactivity", J. Am. Chem. Soc. 2008, 130, 2408. See a highlight in the February 11^th, 2008 issue of Chemical and Engineering News 2008, 86(6), 46.

(26) Bontemps, S.; Bouhadir, G.; Gu, W.; Mercy, M.; Chen, C.-H.; Foxman, B. M.; Maron, L.; Ozerov, O. V.; Bourissou D. "Metallaboratranes Derived from a Triphosphanyl-Borane: Intrinsic C₃ Symmetry Supported by a Z-Type Ligand", Angew. Chem., Int. Ed. 2008, 47, 1481.

(25) Zhu, Y.; Fan, L.; Chen, C.-H.; Finnell,^U S. R.; Foxman, B. M.; Ozerov, O. V. "C-H Oxidative Addition to a (PNP)Ir Center and Ligand-Induced Reversal of Benzyl/Aryl Selectivity", Organometallics 2007, 26, 6701.

(24) Gatard,^P S.; Guo, C.; Foxman, B. M.; Ozerov, O. V. "Thioether, Dinitrogen, and Olefin Complexes of (PNP)Rh: Kinetics and Thermodynamics of Exchange and Oxidative Addition Reactions", Organometallics 2007, 26, 6066.

(23) Fafard, C. M.; Chen, C.-H.; Foxman, B. M.; Ozerov, O. V. "Covalent Palladium-Zinc Bonds and Their Reactivity", Chem. Commun. 2007, 4465.

(22) Gerber,^U L. C. H.; Watson, L. A.; Parkin, S.; Weng, W.; Foxman, B. M.; Ozerov, O. V. "A Bis(methylidene) Complex of Tantalum Supported by a PNP Ligand", Organometallics, 2007, 26, 4866.

(21) Fafard, C. M.; Adhikari, D.; Foxman, B. M.; Mindiola, D. J.; Ozerov, O. V. "Addition of Ammonia, Water, and Dihydrogen Across a Single Pd-Pd Bond", J. Am. Chem. Soc. 2007, 129, 10318.

(20) Weng, W.; Chen, C.-H.; Foxman, B. M.; Ozerov, O. V. "Palladium Complexes of a P₂C= Ligand Containing a Central Carbene Moiety", Organometallics 2007, 26, 3315.

(19) DeMott,^U J. C.; Basuli, F.; Kilgore, U. J.; Foxman, B. M.; Huffman, J. C.; Ozerov, O. V., Mindiola, D. J."Silver(I) and Thallium(I) Complexes of a PNP Ligand and Their Utility as PNP Transfer Reagents", Inorg. Chem. 2007, 46, 6271.

(18) DeMott,^U J. C.; Guo, C.; Foxman, B. M.; Yandulov, D. V.; Ozerov, O. V., "Five-coordinate aluminum complexes of a PNP ligand", Mendeleev Commun. 2007, 17, 63 (invited contribution to the Higher Chemical College issue).

(17) Fafard, C. M.; Ozerov, O. V. "Retardation of beta-Hydrogen Elimination in PNP Pincer Complexes of Pd", Inorg. Chim. Acta, 2007, 360, 286 (invited contribution for the Next Generation issue).

(16) Weng, W.; Parkin, S.; Ozerov, O. V. "Double C-H Activation Results in Ru Complexes of a Neutral PCP Ligand With a Central Carbene Moiety", Organometallics, 2006, 25, 5345.

(15) Ozerov, O. V.; Guo, C.; Foxman, B. M. "Missing Link: PCP Pincer Ligands Containing P-N Bonds And Their Pd Complexes", J. Organomet. Chem. 2006, 691, 4802.

(14) Gatard,^P S.; Çelenligil-Çetin,^PR.; Guo, C.; Foxman, B. M.; Ozerov, O. V. "Carbon-Halide Oxidative Addition and Carbon-Carbon Reductive Elimination at a (PNP)Rh Center", J. Am. Chem. Soc. 2006, 128, 2808.

(13) Weng, W.; Guo, C.; Çelenligil-Çetin,^P R.; Foxman, B. M.; Ozerov, O. V. "Skeletal Change In The PNP Pincer Ligand Leads To A Highly Regioselective Alkyne Dimerization Catalyst", Chem. Commun., 2006, 197.

(12) Ozerov, O. V.; Moura, C. P.; Hoffman, N. W. "Experiments in Thermodynamics and Kinetics of Phosphine Substitution in (p-Cymene)RuCl₂(PR₃)", J. Chem. Ed. 2007, 84, 489.

(11) Fan. L.; Parkin, S.; Ozerov, O. V. "Halobenzenes and Ir(I): Kinetic C-H Oxidative Addition and Thermodynamic C-Hal Oxidative Addition", J. Am. Chem. Soc. 2005, 127, 16772-16773.

(10) Fan, L.; Ozerov, O. V. "Efficient Nickel Catalyst For Coupling Of Acetonitrile With Aldehydes", Chem. Commun. 2005, 4450.

(9) Weng, W.; Guo, C.; Moura, C. P.; Yang, L.; Foxman, B. M.; Ozerov, O. V. "Competitive Activation of N-C and C-H Bonds of the PNP Framework by Monovalent Rhodium and Iridium", Organometallics 2005, 24, 3487-3499.

(8) Scott,^U V. J.; Çelenligil-Çetin,^PR.; Ozerov, O. V. "Room-Temperature Catalytic Hydrodefluorination of Aliphatic C-F Bonds", J. Am. Chem. Soc. 2005, 127, 2852-2853. (See a highlight in the March 14^th, 2005 issue of Chemical and Engineering News 2005, 83(11), 33)

(7) Bailey, B. C.; Huffman, J. C.; Mindiola, D. J.; Weng, W.; Ozerov, O. V. "Remarkably Stable Titanium Complexes Containing Terminal Alkylidene, Phosphinidene and Imide Functionalities", Organometallics 2005, 24, 1390-1393.

(6) Çelenligil-Çetin,^P R.; Watson, L. A.; Guo, C.; Foxman, B. M.; Ozerov, O. V. "Decarbonylation of Acetone and Carbonate at a Pincer-Ligated Ru Center", Organometallics 2005, 24, 186-189.

(5) Weng, W.; Yang, L.; Foxman, B. M.; Ozerov, O. V. "Chelate-Enforced Phosphine Coordination Enables a-Abstraction to Give Zirconium Alkylidenes", Organometallics 2004, 23, 4700-4705.

(4) Ozerov, O. V.; Guo, C.; Fan. L.; Foxman, B. M. "Oxidative Addition of N-C and N-H Bonds to Zero-Valent Nickel, Palladium, and Platinum", Organometallics 2004, 23, 5573-5580.

(3) Fan, L.; Yang, L.; Guo, C.; Foxman, B. M.; Ozerov, O. V. "N-C cleavage in pincer PNP complexes of palladium", Organometallics 2004, 23, 4778-4787.

(2) Ozerov, O. V.; Guo, C.; Papkov, V. A.; Foxman, B. M. "Facile Oxidative Addition of N-C and N-H Bonds to Monovalent Rhodium and Iridium", J. Am. Chem. Soc. 2004, 126, 4792-4793.

(1) Fan, L.; Foxman, B. M.; Ozerov, O. V. "N-H Cleavage as a Route to Palladium Complexes of a New PNP Pincer Ligand", Organometallics 2004, 23, 326-328.

Ozerov group members: Undergraduates^U, Graduate Students, and Postdocs^P.

For Oleg’s pre-Brandeis publications, see here.

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