s

BRUCE M. FOXMAN

Department of Chemistry, Mail Stop 015, Brandeis University, Waltham, MA 02454-9110

Telephone: +1-781-736-2532 (voice); +1-781-736-2516 (fax)

email: foxman1 at brandeis.edu;       web page : https://www.xray.chem.brandeis.edu






EDUCATION

Institution and mentor                                                        Major                                                       Degree and Year

Iowa State University                                                        Chemistry                                                 B. S., 1964
(Senior Research Thesis Advisor :                                                                                                    ("with distinction")
Professor John G. Verkade)

Massachusetts Institute of Technology                               Inorganic Chemistry                               Ph. D., 1968
(Ph. D. Thesis Advisor:
Professor F. Albert Cotton)

The Australian National University                                   Inorganic Chemistry                                 Research Fellow
(Postdoctoral Research Advisor:                                                                                                         1968-72
Professor Alan M. Sargeson)
 

PROFESSIONAL APPOINTMENTS

Research Fellow, The Australian National University, 1968-1972
Assistant Professor, Brandeis University, 1972-1978
Visiting Professor, IBM Thomas J. Watson Research Center, 1975
Associate Professor, Brandeis University, 1978-1985
Professor, Brandeis University, 1985-2018

Emeritus Professor, Brandeis University, 2018-
Visiting Professor, Oxford University, 1987
Visiting Professor, Max-Planck-Institut für Polymerforschung, 1995-1996
Honorary Professor, University of Birmingham, 2001
Professeur Invité, Université Louis Pasteur, Strasbourg, Summer 2002

Brandeis Prize for Excellence in Teaching, 2009

70th Birthday Symposium in Honor of Bruce M. Foxman, American Crystallographic Association National Meeting (Published as ACA Transactions, 2012: https://www.amercrystalassn.org/2012-transactions ) , Boston, 28 July-01 August 2012

Elected Fellow of the Royal Society of Chemistry (FRSC), 2017

Elected Fellow of the American Crystallograhic Association, 2020

 

PROFESSIONAL ACTIVITIES
 

Membership in Professional Societies: American Chemical Society, American Crystallographic Association, Royal Society of Chemistry, Materials Research Society

Member, International Advisory Committee, Vth through XXIIIrd  International Conference on the Chemistry of the Organic Solid State.

 

Member, Editorial Advisory Board, Chemistry of Materials, American Chemical Society, 2001-2006

 

Member, Editorial Advisory Board, Crystal Growth and Design, American Chemical Society, 2000-2011

 

Member, International Editorial Advisory Board, CrystEngComm, Royal Society of Chemistry, 2001-2003

 

Member, Editorial Advisory Board, Journal of Chemical Crystallography, Kluwer Academic Publishers

 

Member, Editorial Advisory Board, Journal of Coordination Chemistry, Taylor & Francis Publishers, 2004-2010

 

Program Chair, American Crystallographic Association National Meeting, Boston, 28 July-01 August 2012

 

Scientific Organizer of the Symposium in Honor of R. D. Adams, 217th National American Chemical Society Meeting, Anaheim, CA, 21-25 March 1999.

 

National Science Foundation, Division of Materials Research and Division of Chemistry Review Panels

 

Member, External Review Panel and Visiting Committee, Center for Materials Research and Analysis, University of Nebraska, Lincoln, NE, December 1989.

 

Invited Lecture Series in X-ray Crystallography, presented at Harvard University, 1981, 1986.

 

Scientific Co-Organizer (with Professor Iain C. Paul) of the Vth International Conference on the Chemistry of the Organic Solid State, held at Brandeis University, 12-16 July, 1978.

 

 

EDUCATIONAL ACTIVITIES

 

Invited Instructor/Lecturer, "UCSD Summer School in Crystallography," sponsored by Pfizer, Inc., University of California at San Diego, 30 July - 08 August 2007.

 

Invited Instructor/Lecturer, "Crystallography for Organic Chemists," an ACS-PRF Summer School, University of California at San Diego, 2-13 August 2004; 01-06 August 2005.

 

Member, ACS Examinations Committee, Conceptual Examination Preparation, 1999-2000.

 

Member, College Board Advanced Placement Chemistry Committee, 1991-1997.

 

Chair, College Board Advanced Placement Chemistry Committee, 1993-1996.

 

Leader of the AP National Teleconference, December, 1994, as Chair of the Advanced Placement Chemistry Program; live teleconference produced by the College Board in conjunction with WEDW Public Television, Stamford, CT.  Broadcast live to over 300 high schools in the USA and Canada. Video tape (90 min., same title) prepared by the College Board for distribution to high school Chemistry AP programs.

 

"The Role of Advanced Placement Science Courses in Educational Reform," panel presentation at the College Board National Forum, Washington, DC, 28 October 1994.

 

"Standardized Examinations and their Impact on Critical Thinking, Scientific Literacy and High School Curricula," presentation to the National Research Council Commission on Physical Sciences, Mathematics and Applications, National Academy of Sciences, Washington, DC, 10 May 1994.

 

Invited Instructor/Lecturer, I Escuela y el XI Congreso Iberoamericano de Cristalografía, Departamento de Química, Facultad des Ciencias, Universidad de Los Andes, Mérida, Venezuela, 2-14 September 1990.

 

PUBLICATIONS, 1964-

1. "Transition Metal Complexes of Caged Phosphite Esters", Verkade, J. G.; Huttemann, T. J.; Foxman, B. M.; McCarley, R. E.; Hendricker, D. G. Proceedings of the 8th I.C.C.C.,Vienna, Austria, 1964, p. 191-193.

2. "Transition Metal Complexes of a Constrained Phosphite Ester. IV. Compounds of Cobalt(I), Cobalt(III), Nickel(II), and Nickel(0)", Huttemann, T. J., Jr.; Foxman, B. M.; Sperati, C. R.; Verkade, J. G. Inorg. Chem. 1965, 4, 950-953.

3. "Structures of Two Compounds Containing Strong Metal-to-Metal Bonds", Bennett, M. J.; Cotton, F. A.; Foxman, B. M.; Stokely, P. F. J. Am. Chem. Soc. 1965, 89, 2759-2760.

4. "The Crystal and Molecular Structure of Trirhenium Nonaiodide", Bennett, M. J.; Cotton, F. A.; Foxman, B. M. Inorg. Chem. 1968, 7, 1563-1569.

5. "The Structure of Oxopentachloropropionatobis(triphenylphosphine)dirhenium", Cotton, F. A.; Foxman, B. M. Inorg. Chem. 1968, 7, 1784-1792.

6. "Some Reactions of the Octahalodirhenate(III) Ions. VIII. The Structure of a Phosphine-Substitution Product of Octahalodirhenate(III)", Cotton, F. A.; Foxman, B. M. Inorg. Chem. 1968, 7, 2135-2140.

7. "The Structure of μ-Oxo-μ-chloro-di-μ-propionato-bis(chlorotriphenylphosphinerhenium). A New Metal-Metal Bond", Cotton, F. A.; Eiss, R.; Foxman, B. M. Inorg. Chem. 1969, 8, 950-957.

8. "Steric Acceleration in the Base Hydrolysis of Some Pentakis(alkylamine)cobalt(III) Complexes", Buckingham, D. A; Foxman, B. M.; Sargeson, A. M. Inorg. Chem. 1970, 9, 1790-1795.

9. "Reactions of Coordinated Nucleophiles. Formation and Structure of a Novel Tridentate Complex", Buckingham, D. A; Foxman, B. M.; Sargeson, A. M.; Zanella, A. J. Am. Chem. Soc. 1972, 94, 1007-1009.

10. "Structural Evidence for Ground-State Steric Effects in Chloropentakis-(methylamine)cobalt(III) Nitrate", Foxman, B. M. Chem. Commun. 1972, 515-516.

11. "X-Ray Molecular Structure of Dicarbonyl-η5-cyclopentadienyl(η2-tetramethylallenyl)iron Tetrafluoroborate. A Sterically Crowded Allene Complex", Foxman, B. M. Chem. Commun.1975, 221-222.

12. "Applications of the King and Lipscomb Expression for the X-Ray Scattering of a Hindered Rotor", Bennett, M. J.; Hutcheon, W. L.; Foxman, B. M. Acta Crystallogr., Sect. A 1975, A31, 488-494.

13. "Cephalotaxine Chemistry: Unusual Addition Reactions of seco-Cephalotaxine Derivatives", Schwab, J. M.; Parry, R. J.; Foxman, B. M. Chem. Commun. 1975, 906-907.

14. "The Two β Forms of Poly(L-glutamic Acid)", Itoh, K.; Foxman, B. M.; Fasman, G. D. Biopolymers 1976, 15, 419-455.

15. "The Mechanism of Formation of Sodium Gallate Superionic Conductors", LaPlaca, S. J.; Foxman, B. M.; Foster, L. M. in Superionic Conductors; Mahan, G. D.; Roth, W. L., Eds.; Plenum Press: New York, N.Y., 1976; pp. 419-420.

16. "Synthesis, Stereoisomerism, and Fluxional Behavior of Cationic Alleneiron Complexes", Foxman, B.; Marten, D.; Rosan, A.; Raghu, S.; Rosenblum, M. J. Am. Chem. Soc. 1977, 99, 2160-2165.

17. "Molecular Structure and Dynamics of TaCl(h4-C10H8)[(CH3)2PC2H4P(CH3)2]2", Albright, J. O.; Brown, L. D.; Datta, S.; Kouba, J. K.; Wreford, S. S.; Foxman, B. M. J. Am. Chem. Soc. 1977, 99, 5518-5519.

18. "Polymerization of NiBr2[P(CH2CH2CN)3]2: A `Triply-Specific' Solid-State Reaction", Cheng, K.; Foxman, B. M. J. Am. Chem. Soc. 1977, 99, 8102-8103.

19. "Cyclophanes. 13. Crystal and Molecular Structure of [2.2](2.5)-Furano-(1,4)naphthalenophane", Keehn, P. M.; Foxman, B. M.; Corson, M. Tetrahedron 1978, 34, 1641-1649.

20. "Comparative Crystallography of Sterically Crowded Transition-Metal Complexes. I. Structures of [Co(NH2CH3)5Cl](NO3)2 and [Cr(NH2CH3)5Cl]Cl2", Foxman, B. M. Inorg. Chem. 1978, 17, 1932-1938.

21. "Preparation and Molecular Structure of [(h-C5H5)2Ta(Me2PC2H4PMe2]Cl·CH3CN", Foxman, B. M.; McNeese, T. J.; Wreford, S. S. Inorg. Chem. 1978, 17, 2311-2314.

22. "Preparation and Molecular Structure of [Ta{H2Al[OC2H4OMe)2}(Me2PC2H4PMe2)2]2, a Co-ordinatively Unsaturated Aluminohydride Adduct of Tantalum(I)", McNeese, T. J.; Wreford, S. S.; Foxman, B. M. Chem. Commun. 1978, 500-501.

23. "Crystal and Molecular Structure of {Ni[(CH3)2C(OH)CH2COCH3]2}{Ni-[NCS]4[P(CH2CH2CN)3]2}: A β-Hydroxy Ketone Chelate Complex", Foxman, B. M.; Mazurek, H. Inorg. Chem. 1979, 18, 113-116.

24. "Ligand Exchange in TaX(η4-naphthalene)(Me2PCH2CH2PMe2)2: The Pentagonal Bipyramid to Monocapped Trigonal Prism Traverse", Albright, J. O.; Datta, S.; Dezube, B.; Kouba, J. K.; Marynick, D. S.; Wreford, S. S.; Foxman, B. M. J. Am. Chem. Soc. 1979, 101, 611-619.

25. "Simultaneous Polymerization and Crystallization: A New Method for the Preparation of Mixed-metal Coordination Polymers", Foxman, B. M.; Gersten, S. W. Inorg. Chim. Acta 1979, 33, L151-L152.

26. "An Introduction to the Solid State Polymerization of Transition-metal Complexes", Cheng, K.; Foxman, B. M.; Gersten, S. W. Mol. Cryst. Liq. Cryst. 1979, 52, 77-82.

27. "Biosynthesis of the Cephalotaxis Alkaloids. Investigations of the Early and Late Stages of Cephalotaxine Biosynthesis", Parry, R. J.; Chang, M. N. T.; Schwab, J. M.; Foxman, B. M. J. Am. Chem. Soc. 1980, 102, 1099-1111.

28. "The Preparation and Properties of Cationic Dicarbonylcyclopentadienyliron Complexes of Organic Carbonyl Compounds: Molecular Structure of Dicarbonylcyclopenta-dienyliron(3-Methylcyclohexenone) Hexafluorophosphate", Foxman, B. M.; Klemarczyk, P. T.; Liptrot, R. E.; Rosenblum, M. J. Organometal. Chem. 1980, 187, 253-265.

29. "Preparation and Molecular Structure of TaH[P(C6H5)2]2[(CH3)2PC2H4P(CH3)2]2, a Metal Hydride of the Type MHL2(bidentate phosphine)+ Having a Pentagonal-Bipyramidal Structure", Domaille, P. J.; Foxman, B. M.; McNeese, T. J.; Wreford, S. S. J. Am. Chem. Soc. 1980, 102, 4114-4120.

30. "Synthetic Applications of the Chemistry of Dicarbonyl Cyclopentadienyliron Complexes", Rosenblum, M.; Chang, T. C. T.; Foxman, B. M.; Samuels, S. B.; Stockman, C. in Organic Synthesis; Trost, B. M.; Hutchinson, C. R., Eds.; IUPAC, Pergamon Press: N.Y., 1981; pp 47-54.

31. "Conformational Polymorphism of Ni(NCS)2[P(CH2CH2CN)3]2. A Crystallographic Study of Three Polymorphs", Foxman, B. M.; Goldberg, P. L.; Mazurek, H. Inorg. Chem. 1981, 20, 4368-4375.

32. "Reactivity of Distorted C5H5Fe(CO)2(olefin) Cations toward Nucleophilic Attack", Chang, T. C. T.; Foxman, B. M.; Rosenblum, M.; Stockman, C. J. Am. Chem. Soc. 1981, 103, 7361-7362.

33. "Base-Catalyzed Condensation of a Coordinated Amine and a Nitrile to Form a Tridentate Amidine, [Co(en)(NH2CH2CH2NC(NH2)CH2NH2X]+2 (X = Cl, Br), and the Subsequent Hydrolysis of Halide", Buckingham, D. A.; Clark, C. R.; Foxman, B. M.; Gainsford, G. J.; Sargeson, A. M.; Wein, M.; Zanella, A. Inorg. Chem. 1982, 21, 1986-1997.

34. "Structure of Tris(2-cyanoethyl)phosphine Oxide", Foxman, B. M.; Kim, C. H.; Mazurek, H. Acta Crystallogr., Sect. B 1982, B38, 1622-1624.

35. "The Structure and Solid-State Reactivity of a New Polymorph of Tetrakis(4-vinylpyridine)diisothiocyanatocobalt(II)", Foxman, B. M.; Mazurek, H. Inorg. Chim. Acta 1982, 59, 231-235.

36. "DL-threo-β-Fluoroaspartate and DL-threo-β-Fluoroasparagine: Selective Cytotoxic Agents for Mammalian Cells in Culture", Stern, A. M.; Foxman, B. M.; Tashjian, A. H., Jr.; Abeles, R. H. J. Med. Chem.1982, 25, 544-550.

37. "The Crystal Structure of Tetratellurotetracene (TTeT) and Polymorphism of Tetraselenotetracene (TseT)", Sandman, D. J.; Stark, J. C.; Hamill, G. P.; Burke, W. A.; Foxman, B. M. Mol. Cryst. Liq. Cryst. 1982, 86, 79-85.

38. "5,6:11,12-Bis(ditelluro)tetracene: Synthesis, Molecular, and Supramolecular Properties", Sandman, D. J.; Stark, J. C.; Foxman, B. M. Organometallics1982, 1, 739-742.

39. "Synthesis and X-Ray Crystal Structure of Dipotassium [Tris(3,5-di-t-butylpyro-catecholato)manganate(IV)]-Acetonitrile (1/6), A Novel Mn(IV) Tris(bidentate) Chelate", Hartman, J. A. R.; Foxman, B. M.; Cooper, S. R. Chem. Commun. 1982, 583-584.

40. "Reactive Charge-Transfer Complexes as Precursors for New Organometallic Salts. Synthesis and Structure of [(h5-C5H5)2Fe].5[(NC)2C=C-(CN)O]-", Sullivan, B. W.; Foxman, B. M. Organometallics 1983, 2, 187-189.

41. "Crown Thiaether Chemistry. Crystal Structure of 1,4,8,10,13,16-Hexathia-cyclooctadecane, the Hexathia Analogue of 18-Crown-6", Hartman, J. A. R.; Wolf, R. E.; Foxman, B. M.; Cooper, S. R. J. Am. Chem. Soc. 1983, 105, 131-132.

42. "A Sterically Crowded Organopentacycanocobaltate: Single-Crystal X-Ray Structure Determination and Reactivity Study of K6[(NC)5CoC(COOCH3)=C-(COOCH3)Co(CN)5·6 H2O", Grande, K. D.; Kunin, A. J.; Stuhl, L. S.; Foxman, B. M. Inorg. Chem. 1983, 22, 1791-1794.

43. "Development of New Technologies for Solid-State Polymerization -- A Conceptual and Experimental Approach", Foxman, B. M.; Jaufmann, J. D. J. Polym. Sci., Polym. Symp.1983, 70, 31-43.

44. "Studies of the Solid State Properties of Molecular and Supramolecular Selenium and Tellurium Materials", Sandman, D. J.; Stark, J. C.; Rubner, M.; Acampora, L. A.; Samuelson, L. A.; Foxman, B. M. Mol. Cryst. Liq. Cryst. 1983, 93, 293-305.

45. "Dichlorobis(3,3',3"-phosphinidynetripropionitrile)nickel(II) and dibromobis(3,3',3"-phosphinidyne-tripropionitrile)nickel(II) Monomers and Polymers", Foxman, B. M.; Jaufmann, J.; Sullivan, B. Inorg. Syn. 1983, 22, 113-115.

46. "Higher Valent Manganese Chemistry. Synthetic, Structural, and Solution Studies on [Mn(catecholate)3]n- ( n = 2, 3) Complexes", Hartman, J. R.; Foxman, B. M.; Cooper, S. R. Inorg. Chem.1984, 23, 1381-1387.

47. "Anionic Alkyne Complexes of Tungsten", Maher, J. M.; Fox, J. R.; Foxman, B. M.; Cooper, N. J. J. Am. Chem. Soc. 1984, 106, 2347-2353.

48. "Synthesis, Structure and Reactivity of a Polynuclear Chromium Tetraanion, Tetrakis ((μ3-methoxo)tricarbonylchromate (0))", McNeese, T. J.; Cohen, M. B; Foxman, B. M. Organometallics 1984, 3, 552-556.

49. 1,8:4,5-Bis(diseleno)naphthalene", Stark, J. C.; Reed, R.; Acampora, L. A.; Sandman, D. J.; Jansen, S.; Jones, M. T; Foxman, B. M. Organometallics1984, 3, 732-735.

50. "Metal Salts and Complexes as Structural Models and Templates for the Solid State Polymerization of Substituted Acetylenes", Foxman, B. M.; Jaufmann, J. D. Mol. Cryst. Liq. Cryst. 1984, 106, 187-197.

51. "Studies of the Solid State Reactivity and Properties of Diacetylene Polymers and Acetylenes", Sandman, D. J.; Hamill, G. P.; Samuelson, L. A.; Foxman, B. M. Mol. Cryst. Liq. Cryst. 1984, 106, 199-217.

52. "Synthetic, Structural, and Electrical Aspects of Molecular and Polymeric Selenium and Tellurium Materials", Sandman, D. J.; Stark, J. C.; Acampora, L. A.; Samuelson, L. A.; Allen, G. W.; Jansen, S.; Jones., M. T.; Foxman, B. M. Mol. Cryst. Liq. Cryst. 1984, 107, 1-17.

53. "Isolation and Characterization of (PNP)2Co(CN)4, an Unusual Square Planar Cobalt(II) Complex", Carter, S. J.; Foxman, B. M.; Stuhl, L. S. J. Am. Chem. Soc. 1984, 106, 4265-4266.

54. "Cofacial Metallocenes. Synthesis and Crystal Structure of 1,8-diferrocenylnaphthalene", Lee, M.-T.; Foxman, B. M.; Rosenblum, M. Organometallics 1985, 3, 539-547.

55. "An Approach to the Synthesis of Neplanocin A", Faith, W. C.; Booth, C. A.; Foxman, B. M.; Snider, B. B. J. Org. Chem. 1985, 50, 1983-1985.

56. "ESR and Theoretical Studies of bis-Benzene-1,2-Diselenolate Nickel and Related Complexes", Jones, M. T.; Jansen, S.; Sandman, D. J.; Foxman, B. M.; Ashwell, G. J. Mol. Cryst. Liq. Cryst. 1985, 125, 429-437.

57. "The Ferric Chloride -Diamine System. 3. X-ray Crystallographic, Magnetic Susceptibility, and Zero- and High-Field Mossbauer Spectroscopy Investigation of [Fe(2,2'-bpy)2Cl2][FeCl4]: Slow Paramagnetic Relaxation and Magnetic Ordering of Complex Bimetallic Salts", Witten, E. H.; Reiff, W. M.; L´a;z´a;r, K.; Sullivan, B. W.; Foxman, B. M. Inorg. Chem. 1985, 24, 4585-4591.

58. "Single Crystal Reactions of Metal Complexes and Salts", Booth, C. A.; Jaufmann, J. D.; Foxman, B. M. Polym. Prepr. (Am. Chem. Soc. Div. Poly. Chem.) 1986, 54, 206-209.

59. "Structure, Reactivity and Electrochemistry of Free-Base β-Oxoporphyrins and Metallo-β-oxoporphyrins", Stolzenberg, A. M.; Glazer, P. A.; Foxman, B. M. Inorg. Chem. 1986, 25, 983-991.

60. "Crystal and Molecular Structure of an Unreactive Methacrylate Phase, Cu2[C3H5COO]4·2[C3H5COOH]", Shepherd, J. W., III; Foxman, B. M. Mol. Cryst. Liq. Cryst. 1986, 137, 87-99.

61. "Octahedral d3 and d4 Complexes of Molybdenum with 1,2-Bis(dimethylphosphino)ethane", Fong, L. K.; Fox, J. R.; Foxman, B. M.; Cooper, N. J. Inorg. Chem. 1986, 25, 1880-1886.

62. "Cobalt(II) Cyanides in Aprotic Media: Effect of Varying Counterion and Solvent", Carter, S. J.; Foxman, B. M.; Stuhl, L. S. Inorg. Chem.1986, 25, 2888-2894.

63. "Coordination Polymers", Foxman, B. M.; Gersten, S. W. in Encyc. Polym. Sci. Eng.; Mark, H.; Bikales, N.; Overberger, C. A.; Menges, F., Eds.; Wiley: New York, 1986; Vol. 4; pp. 175-192.

64. "Asymmetric Carbon-Carbon Bond Formation Using Optically Active (h-C5H5)Fe(CO)2-Vinyl Ether Complexes. Asymmetric Control at Two Adjacent Carbon Centers", Rosenblum, M.; Turnbull, M. M.; Foxman, B. M. Organometallics 1986, 5, 1062-1063.

65. "Direct Synthesis of Low-Valent Acyl Isocyanide Metal Complexes. Preparation, Structure and Properties of (h5-C5H5)Co(CNCOR)2 Complexes Formed via Reaction of (h5-C5H5)Co(CO)2 with Acyl Isocyanides", Carter, S. J.; Foxman, B. M.; Stuhl, L. S. Organometallics1986, 5, 1918-1920.

66. "Stereoselective Synthesis of 1,2-Diethoxy- and 1,4-Dioxino[2,3-b]Furans Using Organoiron Reagents", Rosenblum, M; Foxman, B. M.; Turnbull, M. M. Heterocycles1987, 25, 419-431.

67. "The Nickel, Cobalt, and Copper Complexes of o-Benzenediselenolate: Synthesis and Structural and Magnetic Properties", Sandman, D. J.; Allen, G. W.; Acampora, L. A.; Stark, J. C.; Jansen, S.; Jones, M. T.; Ashwell, G. J.; Foxman, B. M. Inorg. Chem. 1987, 26, 1664-1669.

68. "The Design of a Solid-State Reaction: The Crystal Structure and Solid-State Polymerization of Bis(propiolato)tetraaquozinc(II)", Booth, C. A.; Foxman, B. M.; Jaufmann, J. D. in Crystallographically Ordered Polymers; Sandman, D. J., Ed.; ACS Symposium Series 337; American Chemical Society: Washington, DC, 1987; pp. 95-105.

69. "Metallacyclopentene/Metallaoxanorbornadiene Chemistry. Synthesis, Characterization, and Reactivity of 1-(Cyclopentadienyl)cobalta-2-oxanorbornadiene Complexes", Stolzenberg, A. M.; Scozzafava, M.; Foxman, B. M. Organometallics1987, 6, 769-777.

70. "Crown Thiaether Chemistry. Structural and Conformational Studies of Tetrathia-12-crown-4, Pentathia-15-crown-5, and Hexathia-18-crown-6; Implications for Ligand Design", Wolf, R. E., Jr.; Hartman, J. R.; Storey, J. M. E.; Foxman, B. M.; Cooper, S. R. J. Am. Chem. Soc. 1987, 109, 4328-4335.

71. "Vinylation of Cyclohexane Enolates Using Vinyl Ether-Iron Complexes. Diastereo-selectivity of Carbon-Carbon Bond Formation", Chang, T. C. T.; Foxman, B. M.; Coolbaugh, T. S.; Rosenblum, M.; Simms, N.; Stockman, C. Organometallics1987, 6, 2394-2404.

72. "Optically Active Organoiron Complexes. Preparation and Chemistry", Turnbull, M. M.; Foxman, B. M.; Rosenblum, M. Organometallics 1988, 7, 200-210.

73. "Steric and Electronic Interactions Between Cofacial Metallocene Rings", Arnold, R.; Foxman, B. M.; Rosenblum, M.; and Euler, W. B. Organometallics1988, 7, 1253-1259.

74. "The Interaction of Vacuum Ultraviolet Light with Crystalline Monoacetylenes: A Progress Report", Sandman, D. J.; Velazquez, C. S.; Hamill, G. P; Foxman, B. M.; Preses, J. M.; Weston, R. E., Jr. Mol. Cryst. Liq. Cryst. 1988, 156, 103-108.

75. "Structural and Magnetic Studies of Electrochemically Crystallized Halides of 1,4,5,8-Tetraselenonaphthalene (TSeN)", Acampora, L. A.; Elman, B. S.; Sandman, D. J.; Jansen, S.; Jones, M. T.; Rataiczak, R. D.; Foxman, B. M. Inorg. Chem. 1989, 28, 1579-1582.

76. "Dyotropic Rearrangement in Homochiral Organoiron Complexes Resulting in Inversion at Two Adjacent Carbon Centers", Chu, K.-H.; Foxman, B. M.; Rosenblum, M.; Zhu, X.-Y. Organometallics 1990, 9, 3010-3012.

77. "Lewis Acid Catalyzed Diels-Alder Reactions of 1,4-Benzoquinones: the Reaction Pathway Depends on the Lewis Acid", Hendrickson, J. B.; Haestier, A. M.; Stieglitz, S. G.; Foxman, B. M. New J. Chem. 1990, 14, 689-693.

78. "Synchrotron White Radiation Topographic Studies of the X-ray Induced Solid State Polymerization of Bis(propiolato)tetraaquozinc(II) Single Crystals", Dudley, M.; Hou, S. Y.; Foxman, B. M. Mol. Cryst. Liq. Cryst. 1990, 187, 207-213.

79. "The Synthesis and Structure of Stibaindoles", Buchwald, S. L.; Fisher, R. A.; Foxman, B. M. Angew. Chem., Int. Ed. Engl. 1990, 29, 771-772.

80. "Condensation of Ethyl Mandelate with a Cinnamate Ester: Bicyclocarbolactone Formation", Anastas, P. T.; Foxman, B. M.; McKittrick, B. A.; Stevenson, R. J. Chem. Res. 1991, 54-55.

81. "Manganese(III)-Based Asymmetric Oxidative Free-Radical Cyclization of Unsaturated -Keto Sulfoxides", Snider, B. B.; Wan, B. Y.; Buckman, B. O.; Foxman, B. M. J. Org. Chem. 1991, 56, 328-334.

82. "Stereospecific γ-ray-induced Trimerization of Crystalline Sodium trans-2-Butenoate", de Delgado, G. C. D.; Wheeler, K. A.; Snider, B. B.; Foxman, B. M. Angew. Chem., Int. Ed. Engl. 1991, 30, 420-422.

83. "Crystal and Molecular Structure of a Segment of a Stacked Face-to-face Ferrocene Polymer", Foxman, B. M.; Gronbeck, D. A.; Rosenblum, M. J. Organometal. Chem. 1991, 413, 287-294.

84. "Bis(p-chlorocinnmate) Ester of 2,4-Hexadiyne-1,6-diol: Crystallographic and Spectroscopic Studies of an Unreactive Crystal", Sandman, D. J.; Haaksma, R. A.; Foxman, B. M. Chem. Mater. 1991, 3, 471-475.

85. "Experimental Determination of Single-Ion Anisotropies in Two Nickel Complexes", Landee, C. P.; Mudgett, D. M.; Foxman, B. M. Inorg. Chim. Acta 1991, 186, 45-49.

86. "Structure and Solid State Reaction of Tris(propynoato)scandium(III), an Unusual Coordination Polymer", Brodkin, J. S.; Foxman, B. M. Chem. Commun. 1991, 1073-1075.

87. "Conformational Analysis of Pseudo Cyclic-hexapeptides Based on Quantitative Circular Dichroism (CD), NOE and X-Ray Data. The Pure CD Spectra of Type I and Type II β-Turns", Perczel, A.; Holl´o;si, M.; Foxman, B. M.; Fasman, G. D. J. Am. Chem. Soc. 1991, 113, 9772-9784.

88. "Characterization of Defects in p-Terphenyl Single Crystals", Dudley, M.; DiSalvo, R.; Hou, S.-Y.; Foxman, B. M.; Jones, W. Mol. Cryst. Liq. Cryst. 1992, 211, 35-42.

89. "The Structure and Solid State Reactivity of a Cocrystal of Propynoic Acid and 4-(1-Pyrrolidino)-pyridine. A Study of γ-ray-induced vs. Thermal Reactivity",Wheeler, K. A..; Foxman, B. M. Mol. Cryst. Liq. Cryst. 1992, 211, 347-360.

90. "Solid State Reactivity of Metal trans-2-pentenoates", Di, L.; Foxman, B. M. Chem. Mater.1992, 4, 258-259.

91. "The Structures of the Homologous Series of Square-Planar Metallotetrapyrroles (2,3,7,8,12,13,17,18-Octaethylporphyrinato)palladium(II), trans-2,3-Dihydro-2,3,7,8,12,13,17,18-octaethylporphyrinato)- palladium(II), (tct-2,3,7,8-Tetrahydro-2,3,7,8,12,13,17,18-octaethyl-porphyrinato)-palladium(II)", Stolzenberg, A. M.; Schussel, L. J.; Summers, J. S.; Foxman, B. M.; Petersen, J. L. Inorg. Chem. 1992, 31, 1678-1686.

92. "How Reverse Turns May Mediate the Formation of Helical Segments in Proteins: An X-ray Model", Perczel, A.; Foxman, B. M.; Fasman, G. D. Proc. Nat. Acad. Sci. 1992, 89, 8210-8214.

93. "X-ray Diffraction Studies of Diacetylene Polymers, Monomers and Derived Materials", Sandman, D. J.; Velazquez, C. S.; Hamill, G. P.; Foxman, B. M. Polym. Prepr. (Am. Chem. Soc. Div. Poly. Chem.) 1992, 33, 284-285.

94. "Face-to-Face Cyclopentadienes. Reaction Path for the Conversion of 1,8-Bis(cyclopentadienyl)naphthalene to its Diels-Alder Adduct", Foxman, B. M.; Gronbeck, D. A.; Khruschova, N.; Rosenblum, M. J. Org. Chem. 1993, 58, 4078-4082.

95. "Synthesis and Structure of 2,2'-Binaphthalenediyl-Substituted Ferrocenes and Derived Oligomers", Foxman, B. M.; Rosenblum, M.; Sokolov, V.; Khruschova, N. Organometallics1993, 12, 4805-4809.

96. "Mn(III)-Based Oxidative Fragmentation-Cyclization Reactions of Unsaturated Cyclobutanols", Snider, B. B.; Vo, N. H.; Foxman, B. M. J. Org. Chem. 1993, 58, 7228-7237.

97. "Asymmetric Induction in Mn(III)-Based Oxidative Free-Radical Cyclizations of Phenylmenthyl Acetoacetates and 2,5-Dimethylpyrrolidine Acetacetamides", Zhang, Q.; Mohan, R.; Cook, L.; Kazanis, S.; Peisach, D.; Foxman, B. M.; Snider, B. B.. J. Org. Chem.1993, 58, 7640-7651.

98. "Crystallography and Composition of Some New Potassium-Neodymium Silicates", Haile, S.: Wuensch, B. J.; Laudise, R. A.; Opila, R.; Siegrist, T.; Foxman, B. M. Trans. Am. Cryst. Assn. 1991, 27, 77-94.

99. "Cocrystalline Salts of Alkynoic Acids. The Crystal and Molecular Structure of 2-Aminopyridinium Butynoate", Wheeler, K. A.; Foxman, B. M. Mol. Cryst. Liq. Cryst. 1994, 240, 89-98.

100. "Conformational Polymorphism of Di(2-naphthyl) Ditelluride", Sandman, D. J.; Li, L.; Tripathy, S.; Stark, J. C.; Acampora, L.; Foxman, B. M. Organometallics1994, 13, 348-353.

101. "Synthesis, Structure and Solid State Polymerization of Diaquabis(propynoato)magnesium", Case, C. B.; Foxman, B. M. Inorg. Chim. Acta 1994, 222, 339-343.

102. "Structure and Solid-State Reactivity of 2-Aminopyridinium Propynoate", Wheeler, K. A.; Foxman, B. M. Chem. Mater. 1994, 6, 1330-1336.

103. "Chloroketone Hydrolysis by Chymotrypsin and N-Methylhistidyl-57-chymotrypsin: Implications for the Mechanism of Chymotrypsin Inactivation by Chloroketones", Prorok, M.; Albeck, A.; Foxman, B. M.; Abeles, R. H. Biochemistry1994, 33, 9784-9790.

104. "Synthesis, Structure and Solid State Polymerization of Dimethyl(propynoato)thallium", Moloney, M. J.; Foxman, B. M. Inorg. Chim. Acta 1995, 229, 323-328.

105. "Azabenzotriazole (HOAt) Derivatives as Superior Coupling Reagents for Peptide Synthesis", Albericio, F.; Abdelmoty, I.; Bofill, J. M.; Carpino, L. A.; El-Faham, A.; Foxman, B. M.; Gairi, M.; Giralt, E.; Griffin, E. W.; Kates, S. A.; Lloyd-Williams, P.; Minor, C. A.; Scarmoutzos, L. M.; Shroff, H.; Triolo, S.; Wenschuh, H.; in Peptides 1994: Proceedings of the Twenty-Third European Peptide Symposium; Maia, H. L. S., Ed., ESCOM Science Publishers, Leiden, The Netherlands, 1995, p. 23.

106. "Structural Studies of Reagents for Peptide Bond Formation: Crystal and Molecular Structures of HBTU and HATU", Letters in Peptide Science 1994, 1, 57-67; with Abdelmoty, I.; Albericio, F.; Carpino, L. A.; Foxman, B. M.; Kates, S. A.

107. "Oxo Complexes of Tungstenocene via Oxidation of [W(h5-C5H5)2(OCH3)(CH3)] and Related Reactions: Synthesis, Structural Characterization, and Photodisproportionation of the Spin Paired d1-d1 Oxo Bridged Dimer [{W(η5-C5H5)2(CH3)}2(μ-O)]2+ and Synthesis and Characterization of the d0 Terminal Oxo Complex [W(η5-C5H5)2(O)(CH3)]+", Jernakoff, P.; Fox, J. R.; Hayes, J. C.; Lee, S.; Foxman, B. M.; Cooper, N. J. Organometallics 1995, 14, 4493-4504.

108. "A Search for the Ideal Type I b-Turn", Perczel, A.; J´a;kli, I.; Foxman, B. M.; Fasman, G. D. Biopolymers1996, 38, 723-732.

109. "Structure and Solid State Polymerization of 1,6-Bis(3',6'-Dibromo-n-carbazolyl)2,4-hexadiyne (DCHBr4)", Sandman, D. J.; Velazquez, C. S.; Hankin, S. H. W; Foxman, B. M. Macromolecules 1995, 28, 8142-8146.

110. "Preparation, Structure and Solid State Reactivity of Lanthanum Propynoates", Brodkin, J. S.; Foxman, B. M.; Clegg, W.; Cressey, J. T.; Harbron, D. R.; Hunt, P. A.; Straughan, B. P. Chem. Mater. 1996, 8, 242-247.

111. "Stereospecific &g-Ray-Induced Dimerization of Crystalline Bis(trans-but-2-enoato)calcium", Cho, T. H.; Chaudhuri, B.; Snider, B. B.; Foxman, B. M. Chem. Commun. 1996, 1337-1338.

112. "Characterization of Novel TCNQ and TCNE 1:1 and 1:2 Salts of the Tetrakis(dimethyamino)ethylene Dication, [{(CH3)2N}2CC{N(CH3)2}2]2+", Fox, J. R.; Foxman, B. M.; Guarrera, D.; Miller, J. S.; Calabrese, J. C.; Reis, A. H., Jr. J. Mat. Chem.1996, 6, 1627-1631.

113. "Synthesis of (±)-Allocyathin B2 and (+)-Erainacine A", Snider, B. B.; Vo, N. H.; O'Neil, S. V.; Foxman, B. M. J. Am. Chem. Soc. 1996, 118, 7644-7645.

114. "Asymmetric Synthesis of Sesaminone: Confirmation of Its Structure and Determination of Its Absolute Configuration", Maioli, A. T.; Civiello, R. L.; Foxman, B. M.; Gordon, D. M. J. Org. Chem. 1997, 62, 7413-7417.

115. "Environmentally Benign Synthesis Using Crystal Engineering: Steric Accommodation in Non-Covalent Derivatives of Hydroquinones", Foxman, B. M.; Guarrera, D. J.; Taylor, L. D.; van Engen, D.; Warner, J. C. Cryst. Eng. 1998, 1, 109-118.

116. "Attempted Syntheses of Transition Metal and Lanthanide Aminosquarates. The Hydrolysis Problem", Hosein, H.-A.; Hall, L. A.; Lough, A. J.; Desmarais, W.; Vela, M. J.; Foxman, B. M. Inorg. Chem. 1998, 37, 4184-4189.

117. "Solid-State Polymerization of Aquabis(3-butenoato)calcium", Vela, M. J.; Snider, B. B.; Foxman, B. M. Chem. Mater. 1998, 10, 3167-3171.

118. "Solid-State Photodimerization of 2-Phenylethenyl Enamides", Song, F.; Snook, J. H.; Foxman, B. M.; Snider, B. B. Tetrahedron 1998, 54, 13035-13044."

119. "Total Synthesis of (-)-Asperlicin and (-)-Asperlicin C", He, F.; Foxman, B. M.; Snider, B. B. J. Am. Chem. Soc. 1998, 120, 6417-6418.

120. "Synthesis of Desmethylamino FR901483", Snider, B. B.; Lin, H.; Foxman, B. M. J. Org. Chem. 1998, 63, 6442-6443.

121. "Total Synthesis of (±)-Isosteviol and (±)-Beyer-15-ene-3,19-diol by Manganese(III)-Based Oxidative Quadruple Free-Radical Cyclization", Snider, B. B.; Kiselgof, J. Y.; Foxman, B. M. J. Org. Chem. 1998, 63, 7945-7952.

122. "Reactive Crystals: Design and Discovery", Foxman, B. M.; Vela, M. J. Trans. Amer. Cryst. Assn. 1998, 33, 75-84.

123. "Single Crystal X-Ray Structures of 2-Pyridinecarboxaldehydeazine and Biacetylazine: Implications of the Conjugation in Systems with Carbon-Nitrogen Double Bonds", Kesslen, E. C.; Euler, W. B.; Foxman, B. M. Chem. Mater.1999, 11, 336-340.

124. "Two- and Three-Dimensional Cadmium Coordination Polymers Based on N,N-(2-Pyridyl)-(4-Pyridylmethyl)amine", Wang, Z.; Xiong, R.-G.; Foxman, B. M.; Wilson, S. R.; Lin, W. Inorg. Chem. 1999, 38, 1523-1528.

125. "Synthesis of the Tricyclic Triamine Core of Martinelline and Martinellic Acid", Snider, B. B.; Anh, Y.; Foxman, B. M. Tetrahedron Lett. 1999, 40, 3339-3342.

126. "Nanoporous, Interpenetrated Metal-Organic Diamondoid Networks", Evans, O. R.; Wang, Z.; Xiong, R.-G.; Foxman, B. M.; Lin, W. Inorg. Chem. 1999, 38, 2969-2973.

127. "Coordination Chemistry of 2,4'-Bipyridine. Synthesis and Structures of Co(2,4'-bipyridine)2(NO3)2(H2O) and Cd(2,4'-bipyridine)2(NO3)2(H2O)2", Wang, Z.; Xiong, R.-G.; Naggar, E.; Foxman, B. M.; Lin, W. Inorg. Chim. Acta 1999, 288, 215-219.

128. "Non-Covalent Derivatives of Hydroquinone: Bis-(N,N-Dialkyl)bicyclo[2.2.2]octane-1,4-Dicarboxamide Complexes", Foxman, B. M.; Guarrera, D. J.; Pai, R.; Tassa, C.; Warner, J. C. Cryst. Eng. 1999, 2, 55-64.

129. "Cocrystalline Salts of Alkynoic Acids. II. The Crystal and Molecular Structure of 5-bromo-2-aminopyridinium Propynoate", Vaday, S.; Foxman, B. M. Cryst. Eng. 1999, 2, 145-151.

130. "Synthesis and Reactivity of the Tl(I) salts of [TCNE]- and [TCNE]2-. The Structural Determination of Tl[TCNE] and [TDAE][TCNE]2 and Evidence for a Chelated [TCNE]-", Johnson, M. T.; Campana, C. F.; Foxman, B. M.; Desmarais, W.; Vela, M. J.; Miller, J. S. Chem. Eur. J. 2000, 6, 1805-1810.

131. "Luminescent Lanthanide Coordination Polymers", Ma, L.; Evans, O. R.; Foxman, B. M. Lin, W. Inorg. Chem. 1999, 38, 5837-5840.

132. "Side Group Interactions in a Polydiacetylene Single Crystal", Foley, J. L.; Li, L.; Sandman, D. J.; Vela, M. J.; Foxman, B. M.; Albro, R.; Eckhardt, C. J. J. Am. Chem. Soc. 1999, 121, 7262-7263.

133. "Synthesis and Properties on New Stacked Metallocene Polymers", Hudson, R. D. A.; Foxman, B. M.; Rosenblum, M. Organometallics 1999, 18, 4098-4106.

134. "Design of a New Reactive Phase Using Ammonia as an Ancillary Ligand: Structure and Reactivity of Diamminebis(propynoato)zinc", Ruth, M. B.; Foxman, B. M. Mol. Cryst. Liq. Cryst. 2001, 356, 61-70.

135. 
"New Face-to-Face Metallocene Triads", Hudson, R. D. A; Foxman, B. M.; Rosenblum, M. Organometallics 2000, 469-474.

136. 
"Total Syntheses of (±)-Anchinopeptolide D and (±)-Cycloanchinopeptolide D", Snider, B. B.; Song, F.; Foxman, B. M. J. Org. Chem. 2000, 65, 793-800.

137.  
"Structure and γ-ray Induced Solid-State Polymerization of Sodium Propynoate: Influence of Bilayer Formation on Solid-State Reactivity", Jaufmann, J. D.; Case, C. B.; Sandor, R. B.; Foxman, B. M.  J. Solid State Chem. 2000, 152, 99-104.

138.  
"Bilayer Formation in Metal Carboxylate Structures: Results from the Cambridge Structural Database", Vela, M. J.; Foxman, B. M. Cryst. Eng. 2000, 3, 11-31.

139. 
"The Solid-State Polymerization of 3,5-Dihalo-4-aminobenzoylchlorides: New Structural Perspectives", Sandor, R. B.; Foxman, B. M. Tetrahedron 2000, 56, 6805-6812.

140. 
"The Solid-State Polymerization of Styryl Monomers: A Structural Perspective", Di, L.; Foxman, B. M. Supramolecular Chemistry 2001, 13, 163-174.

141.      "Comparison of the Effects of 5-HOAt and 6-HOAt on Model Peptide Coupling Reactions Relative to the Cases for the 4- and 7-isomers", Carpino, L. A.; Imazumi, H.; Foxman, B. M.;  Vela, M. J.; Henklein, P.; El-Faham, A.; Klose, J.; Bienert, M. Org. Lett. 2000, 2, 2253-2256.

 

142.          "Solid-State Polymerization of Bis(3-butenoato)zinc: Synthesis of a Stereoregular Oligomer", Vela, M. J.; Buchholz, V.; Enkelmann, V.; Snider, B. B.; Foxman, B. M. Chem. Commun. 2000, 2225-2226.

 

143.          "Structure and Magnetic Properties of Binuclear Cu2(O2CCH=CHCH3)4(DMF)2:  A Carboxylate-Bridged Cu(II) Spin Dimer", Schlam, R. F.; Perec, M.; Calvo, R.; Lezama, L.;  Insausti, M.; Rojo, T.;  Foxman, B. M.  Inorg. Chim. Acta 2000, 310, 81-88.

 

144.          "Aquabis(crotonato)bis(pyridine)copper(II)", Baggio, R.; Foxman, B.; Garland, M. T.; Perec, M.; Shang, W. Acta Crystallogr. 2000, C56, e505-e506.

 

145.          "N-(3-Cyano-2-propynyl)carbazole: Synthesis, Crystal Structure and Solid-State Reactivity", Drechsler, U.; Sandman, D. J.; Foxman, B. M. J. Chem. Soc., Perkin 2 Trans. 2001, 581-584.

 

146.          "First Row Transition Metal Complexes of 3-Phenyl-4-hydroxycyclobut-3-ene-1,2-dione (Phenylsquarate)", Williams, A.; Alleyne, B. D.; Hosein, H.-A.; Jaggernauth, H.; Hall, L. A.; Foxman, B. M. Inorg. Chim. Acta 2001, 313, 56-64.

 

147.          "The Solid State and Solution Structure of HAPyU", Carpino, L. A.; Henklein, P.; Foxman, B. M.; Abdelmoty, I.; Costisella, B.; Wray, V.; Domke, T.; El-Faham, A.; Mügge, C.  J. Org. Chem. 2001, 5245-5247.

 

148.          "Synthesis, X-ray Structures, and Magnetic Properties of Copper(II) Pyridinecarboxylate Coordination Networks", Chapman, M. E.; Ayyappan, P.; Foxman, B. M.; Yee, G. T., Lin, W.  Cryst. Growth Des. 2001, 1, 159-163.

 

149.          "New Open Frameworks Based on Metal Pyridylphosphonates", Ayyappan, P.; Evans, O. R.; Foxman, B. M.; Wheeler, K. A.; Warren, T. H.; Lin, W.  Inorg. Chem. 2001, 40, 5954-5961.

 

150.          "Professor Myron Rosenblum's Contributions to Organic Chemistry", Hudson, R. D. A.; Foxman, B. M.  J. Organometal. Chem. 2001, 630, 1-3.

 

151.          "Purification, Crystallization and Molecular Symmetry of CDP-D-glucose 4,6-dehydratase from Yersinia pseudotuberculosis", Vogan, E. M.; Bellamacina, C. R.; He, X. M.; Foxman, B. M.; Ringe, D.; Liu. H. W.; Petsko, G. A.  Acta Crystallogr., Sect. D 2002, 58, 370-373.

 

152.          "The Uronium/Guanidinium Peptide Coupling Reagents: Finally the True Uronium Salts", Carpino, L. A.; Imazumi, H.; El-Faham, A.; Ferrer, F. J.; Zhang, C.; Lee, Y.; Foxman, B. M.; Henklein, P.; Hanay, C.; Mügge, C.; Wenschuh, H.; Klose, J.; Beyermann, M.; Bienert, M.  Angew. Chem., Int. Ed. Engl., 2002, 41, 442-445.

 

153.          "Characterization of intermolecular interactions in a disordered solid via a one-dimensional Patterson synthesis", Chao, M.H.; Harris, K. D. M.; Kariuki, B. M.; Bauer, C. L.; Foxman, B. M. J. Phys. Chem. 2002, 106, 4032-4035.

 

154.          "Pi effects involving Rh-PZ(3) compounds. The quantitative analysis of ligand effects (QALE) ", Wilson, M. R. , Prock, A., Giering, W.P., Fernandez, A. L., Haar, C. M., Nolan,  S. P., Foxman, B. M. Organometallics, 2002, 21, 2758-2763.

 

155.          "A straightforward and effective procedure to test for preferred orientation in polycrystalline samples prior to structure determination from powder diffraction data", Cheung, E. Y.; Harris, K. D. M.; Foxman, B. M. Cryst. Growth. Des. 2003, 3, 705-710.

 

156.          "N-H Cleavage as a Route to Palladium Complexes of a New PNP Pincer Ligand", Fan, L.; Foxman, B. M.; Ozerov, O. V. Organometallics 2004; 23, 326-328.

 

157.          "Structure, polymorphism, and thermal properties of phenyliminoisoindolines", Zhang, Z.; Uth, S; Sandman, D. J.; Foxman, B. M. J. Phys. Org. Chem. 2004, 17, 769-776.

 

158.          "Facile Oxidative Addition of N-C and NH Bonds to Monovalent Rhodium and Iridium,@ Ozerov,O. V.; Guo, C.; Papkov, V. A.; Foxman, B. M. J. Am. Chem. Soc. 2004, 126, 4792-4793.

 

159.          "Diiminoisoindoline: tautomerism, conformations, and polymorphism", Zhang, Z.-Q.; Njus, J. M.; Sandman, D. J.; Guo, C.; Foxman, B. M.; Erk, P.; van Gelder, R. Chem. Commun. 2004, 886-887.

 

160.          "Crystal and Molecular Structure of Crotonohydroxamic Acid, and a Preliminary Investigation of the Solid-State Reactivity of the Acid and Its Salts," Hickey, M. B.; Foxman, B. M. Mol. Cryst. Liq. Cryst. 2005, 440, 195-205.

 

161.          "CIF Applications.  CIF2CRY: for Input of Structural CIF Data into the CRYSTALS program," Cooper, R. I.; Foxman, B. M.; Yang, L. J. Appl. Cryst. 2004, 37, 669-671.

 

162.          "Chelate-Enforced Phosphine Coordination Enables a-Abstraction to Give Zirconium Alkylidenes," Weng, W.; Yang, L.; Foxman, B. M.; Ozerov, O. V. Organometallics 2004, 23, 4700-4705.

 

163.          "N-C cleavage in pincer PNP complexes of palladium," Fan, L.; Yang, L.; Guo, C.; Foxman, B. M.; Ozerov, O. V. Organometallics 2004, 23, 4778-4787.

 

164.          \"Oxidative Addition of N-C and N-H Bonds to Zero-Valent Nickel, Palladium, and Platinum," Ozerov, O. V.; Guo, C.; Fan. L.; Foxman, B. M. Organometallics 2004, 23, 5573-5580.

 

165.          "Decarbonylation of Acetone and Carbonate at a Pincer-Ligated Ru Center," Çelenligil-Çetin, R.; Watson, L. A.; Guo, C.; Foxman, B. M.; Ozerov, O. V. Organometallics 2005, 24, 186-189.

 

166.          "Stereocontrolled Creation of Adjacent Quaternary and Tertiary Stereocenters via a Catalytic, Diastereoselective and Enantioselective Conjugate Addition," Li, H.; Wang, Y.; Tang, L.; Wu, F.; Liu, X.; Guo, C.; Foxman, B. M.; Deng, L. Angew. Chem. Int. Ed. 2005, 44, 105-108.

 

167.          "Conformational Polymorphism of Methacrylamide," Guo, C.; Hickey, M. B.; Guggenheim, E. R.; Enkelmann, V.; Foxman, B. M. Chem. Commun. 2005, 2220-2222.

168.          "Noncovalent Derivatives of Hydroquinone: Complexes with Trigonal Planar Tris-(N,N-dialkyl)trimesamides," Cannon, A. S.; Foxman, B. M.; Guarrera, D. J.; Warner, J. C. Cryst. Growth Des. 2005, 5, 407-411.

169.          "Thermal Solid-State Polymerization of p-Ethynylbenzoic Acid," Njus, J. M.; Sandman, D. J.; Yang, L.; Foxman, B. M. Macromolecules 2005, 38; 7645-7652.

170.          "Competitive Activation of N-C and C-H Bonds of the PNP Framework by Monovalent Rhodium and Iridium," Weng, W.; Guo, C.; Moura, C.; Yang, L.; Foxman, B. M.; Ozerov, O. V., Organometallics 2005, 24; 3487-3499.

171.          "Polymorphism of Cinnamic and -Truxillic Acids: New Additions to an Old Story," Abdelmoty, I.; Buchholz, V.; Di, L.; Guo, C.; Kowitz, K.; Enkelmann, V.; Wegner, G.; Foxman, B. M. Cryst. Growth Des. 2005; 5; 2210-2217.

172.          "Pd-Catalyzed Stereoselective Oxidation of Methyl Groups by Inexpensive Oxidants under Mild Conditions: A Dual Role for Carboxylic Anhydrides in Catalytic CbondH Bond Oxidation," Giri, R.; Liang, J.; Lei, J-G.; Li, J.; Wang, D.; Chen, X.; Naggar, I. C.; Guo, C.; Foxman, B. M.; Yu, J-Q.Angew. Chem. Int. Ed. 2005, 44, 7420-7424.

173.          "Carbon-Halide Oxidative Addition and Carbon-Carbon Reductive Elimination at a (PNP)Rh Center," Gatard, S.; Celenligil-Cetin, R.; Guo, C.; Foxman, B. M.; Ozerov, O. V. J. Am. Chem. Soc. 2006; 128; 2808-2809.

174.          "ortho-Hydroxylation of Benzoic Acids with Hydrogen Peroxide at a Non-heme Iron Center," Taktak, S.; Flook, M.; Foxman, B. M.; Que, Jr., L.;. Rybak-Akimova, E. V. Chem. Commun., 2005, 5301-5303.

175.          "Skeletal Change in the PNP Pincer Ligand Leads to a Highly Regioselective Alkyne Dimerization Catalyst," Weng, W.; Guo, G.; Çelenligil-Çetin, R.;. Foxman, B. M.;. Ozerov, O. V. Chem. Commun., 2006, 197-199.

176.          "Crystal and Molecular Structure of Ammonium trans-2-Butenoate, and a Preliminary Investigation of its Solid-State Reactivity," Yang, L; Foxman, B. M. Mol. Cryst. Liq. Cryst. 2006, 456, 25-33.

177.          "Synthesis and Crystallographic Study of 1,6-bis-(N-phenothiazinyl)-2,4-hexadiyne," Sae-Lim, C.; Sandman, D. J.; Foxman, B. M.; Sukwattanasinitt, M. J. Macromol. Sci., Part A 2006, 43, 1929-1936.

178.          "Coordination Chemistry of H2 and N2 in Aqueous Solution. Reactivity and Mechanistic Studies Using trans-FeII(P2)2X2-Type Complexes (P2 = a Chelating, Water-Solubilizing Phosphine)," Gilbertson, J. D.; Szymczak, N. K.; Crossland, J. L.; Miller, W. K.; Lyon, D. K.; Foxman, B. M.; Davis, J.; Tyler, D. R. Inorg. Chem. 2007, 46, 1205-1214.

179.           "Asymmetric Diels-Alder Reaction of 2-Pyrones with Bifunctional Organic Catalysts," Wang, Y.; Li, H.; Wang, Y.-Q.; Liu, Y.; Foxman, B. M.; Deng, L. J. Am. Chem. Soc. 2007, 129, 6364-6365.

180.           "Formal Synthesis of (±)-Platensimycin," Zou, Y.; Chen, C.-H.; Taylor, C. D.; Foxman, B. M.; Snider, B. B. Org. Lett. 2007; 9, 1825-1828.

181.           "Five-coordinate aluminum complexes of a PNP ligand," DeMott, J. C.; Guo, C.; Foxman, B. M.; Yandulov, D. V.; Ozerov, O. V. Mendeleev Communications 2007, 63-65.
182.           "Covalent palladium-zinc bonds and their reactivity," Fafard, C. M.; Chen, C.-H.; Foxman, B. M.; Ozerov, O. V. Chem. Commun. 2007, 4465 - 4467.
183.           "Structure and Photochemical Isomerization of the Dinuclear Gold(I) Halide Bis(diphenylphosphanyl)ethylene Complexes: Correlation Between Quantum Yield and Aurophilicity," Foley, J. B.; Gay, S. E.; Vela, M. J.; Foxman, B. M.; Bruce, A. E.; Bruce, M. R. M. Eur. J. Inorg. Chem. 2007, 31, 4946-4951.
184.           "Silver(I) and Thallium(I) Complexes of a PNP Ligand and Their Utility as PNP Transfer Reagents," DeMott, J. C.; Basuli, F.; Kilgore, U. J.; Foxman, B. M.; Huffman, J. C.; Ozerov, O. V.; Daniel J. Mindiola, D. J. Inorg. Chem. 2007, 46, 6271-6276.
185.           "Missing link: PCP pincer ligands containing P-N bonds and their Pd complexes," Ozerov, O. V.; Guo, C.; Foxman, B. M. J. Organometal. Chem. 2007, 691, 4802-4806.
186.           "Addition of Ammonia, Water, and Dihydrogen Across a Single Pd-Pd Bond," Fafard, C. M.; Adhikari, D.; Foxman, B. M.; Mindiola, D. J.; Ozerov, O. V. J. Am. Chem. Soc. 2007, 129, 10318-10319.
187.           "Palladium Complexes of a P2C= Ligand Containing a Central Carbene Moiety,"  Weng, W.; Chen, C.-H.; Foxman, B. M.; Ozerov, O. V. Organometallics 2007, 26, 3315-3320.
188.           "Bis(methylidene) Complex of Tantalum Supported by a PNP Ligand," Gerber, L. C. H.; Watson, L. A.; Parkin, S.; Weng, W.; Foxman, B. M.; Ozerov, O. V. Organometallics 2007, 26,  4866-4868.
189.           "Thioether, Dinitrogen, and Olefin Complexes of (PNP)Rh: Kinetics and Thermodynamics of Exchange and Oxidative Addition Reactions," Gatard, S.; Guo, C.; Foxman, B. M.; Ozerov, O. V. Organometallics 2007, 26, 6066-6075.
190.           "C-H Oxidative Addition to a (PNP)Ir Center and Ligand-Induced Reversal of Benzyl/Aryl Selectivity," Zhu, Y.; Fan, L.; Chen, C.; Finnell, S. R.; Foxman, B. M.; Ozerov, O. V. Organometallics 2007, 26, 6701-6703.
191.           "2-Amino-4-methylbenzothiazole,"  Tanke, R. S.; Foxman, B. M. Acta Crystallogr., Sect. E 2007, 63, 4718.
192.           "Molecules in the Solid State," Foxman, B. M.; Ward, M. D. MRS Bulletin 2007, 32, 534-539.
193.           "Metallaboratranes Derived from a Triphosphanyl-Borane: Intrinsic C3 Symmetry Supported by a Z-Type Ligand," Bontemps, S.; Bouhadir, G.; Gu, W.; Mercy, M.; Chen, C.-H.; Foxman, B. M.; Maron, L.; Ozerov, O. V.; Bourissou, D. Angew. Chem., Int. Ed. 2008, 47, 1481-1484.
194.           "Dehydrogenation of Inert Alkyl Groups via Remote C−H Activation: Converting a Propyl Group into a π-Allylic Complex," Giri, R.; Maugel, N.; Foxman, B. M.; Yu, J.-Q.
Organometallics
 2008; 27, 1667-1670.
195.           "Oxidative Addition Reactions of Silyl Halides with the (PNP)Rh fragment," Gatard, S.; Chen, C.-H.; Foxman, B. M.; Ozerov, O. V. Organometallics 2008, 27, 6257-6263.
196.           "Crystal and Molecular Structure of a Second, High-Density Polymorph of Silver Malonate," Reddy, J.; Foxman, B. M. J. Mol. Struct. 2008, 890, 227-231.
197.           "Crystal and Molecular Structure of the bis-Ethyl urethane of 5,7-dodecadiyn-1,12,diol (ETCD)," Wang, X.; Sandman, D. J.; Enkelmann, V.; Chen, C.-H.; Foxman, B. M. J. Macromol. Sci., Part A 2008, 45, 915-917.
198.           "Group 10 and 11 Metal Boratranes (Ni, Pd, Pt, CuCl, AgCl, AuCl and Au+) Derived from a Triphosphine-Borane," Sircoglou, M.; Bontemps, S.;  Bouhadir, G.; Saffon, N.; Miqueu, K.; Gu, W.; Mercy, M.;  Chen, C.-H.; Foxman, B. M.; Maron, L.; Ozerov, O. V.; Bourissou, D. J. Am. Chem. Soc. 2008, 130, 16729-16738.
199.           "Crystal and Molecular Structure of 1-Methyl-6-O-p-toluenesulfonyl-alpha-D-glucopyranoside dihydrate", Kells, H.; Blumstein, A.; Sandman, D. J.; Chen, C.-H.; Foxman, B. M. J. Macromol. Sci., Part A  2009, 46, 1172-1179.
200.           "In Memoriam - Alan McLeod Sargeson (1930-2008)," Foxman, B. M.; Zanella, A.  Comments Inorg. Chem. 2009, 30, 4-6.
201.           "Synthesis, structure determination, and magnetic properties of pentakis-[bis(hexafluoroacetylacetonato)1,2,4-triazinecopper(II)]," Li, L.; Landee, C. P.; Turnbull, M. M.; Foxman, B. M.  J. Coord. Chem. 2009, 62, 1207-1217.
202.           "Multielectron Redox Activity Facilitated by Metal-Metal Interactions in Early/Late Heterobimetallics: Co/Zr Complexes Supported by Phosphinoamide Ligands," Greenwood, B. P.; Rowe, G.; Forman, S. I.; Chen, C.-H.; Foxman, B. M.; Thomas, C. M.  Inorg. Chem. 2009, 48, 6251-6260.
203.           "Copper(II) complexes of 3-amino-1,2,4-triazine and 2-aminopyrazine: Strategies for designing crystalline materials using coordination polymers," Li. L; Turnbull, M. M.; Ackers, J.; Chen, J.; Lin, H.; Pan, B.; Wang, H.; Foxman, B. M.  Inorg. Chim. Acta 2009, 362, 3845-3852.
204.           "Probing the C−H Activation of Linear and Cyclic Ethers at (PNP)Ir," Whited, M. T.; Zhu, Y.; Timpa, S. D.; Chen, C.-H.; Foxman, B. M.; Ozerov, O. V.; Grubbs, R. H. Organometallics 2009, 28, 4560-4570.
205.           "syn,syn-15,17-Di-2-naphthylhexacyclo[10.2.1.13,10.15,8.02,11.04,9]heptadecane deutero-chloroform monosolvate," DeBlase, A. F. ; Thong, D. C.; Nadeau, J. M.; Gebhart, D.; Provo, J.; Foxman, B. M. Acta Cryst., Sect. E, 2009, E65, o2427-o2428.
206.           "Transition metal complexes of 2-amino-3,5-dihalopyridines: Syntheses, structures and magnetic properties of (3,5-diCAPH)2CuX4 and (3,5-diBAPH)2CuX4," Tremelling, G. W.; Foxman, B. M.; Landee, C. P; Turnbull, M. M.; Willett, R. D. Dalton Trans. 2009, 10518-10526.
207.           "Ligand Reactivity in Diarylamido/Bis(Phosphine) PNP Complexes of Mn(CO)3 and Re(CO)3," Radosevich, A. T.; Melnick, J. G.; Stoian, S. A.; Bacciu, D.; Chen, C.-H.; Foxman, B. M.; Ozerov, O. V.; Nocera, D. G.  Inorg. Chem. 2009, 48, 9214-9221.
208.           "High-Spin Manganese(II) Complexes of an Amido/Bis(Phosphine) PNP Ligand," Bacciu, D.; Chen, C. H.; Surawatanawong, P.; Foxman, B. M.; Ozerov, O. V. Inorg. Chem. 2010, 49, 5328-5334.
209.           "Asymmetric Vinylogous Aldol Reaction of Silyloxy Furans with a Chiral Organic Salt," Singh, R. P.; Foxman, B. M.; Deng, L. J. Am. Chem. Soc. 2010, 132, 9558-9560.
210.           "Electronic Factors Affecting Metal−Metal Interactions in Early/Late Heterobimetallics: Substituent Effects in Zirconium/Platinum Bis(phosphinoamide) Complexes," Cooper, B. G.; Fafard, C. M.; Foxman, B. M.; Thomas, C. M. Organometallics 2010, 29, 5179-5186.
211.           "Oxidative addition across Zr/Co multiple bonds in early/late heterobimetallic complexes," Thomas, C. M.; Napoline, J. W.; Rowe, G. T.; Foxman, B. M. Chem. Commun. 2010, 5790-5792. 
212.           "Heterolytic splitting of H-X bonds at a cationic (PNP)Pd center," Gregor, L. C.; Chen, C.-H.; Fafard, C. M.; Fan, L.; Guo, C.; Foxman, B. M.; Gusev, D. G.; Ozerov, O. V. Dalton Trans. 2010, 39, 3195-3202.
213.           "A novel oxazolidinone antibiotic: RWJ-416457," Cheung, E. Y.; Peterson, M. L.; Chiarella, R.; Foxman, B. M. Acta Cryst., Sect. C  2010, C66, o249-o251.
214.           "Carbonate formation within a nickel dimer: synthesis of a coordinatively unsaturated bis(-hydroxo) dinickel complex and its reactivity toward carbon dioxide," Wikstrom, J. P.; Filatov, A. S.; Mikhalyova, E. A.; Shatruk, M.; Foxman, B. M.; Rybak-Akimova, E. V. Dalton Trans. 2010, 39, 2504-2514.
215.           "Metal−Metal Multiple Bonds in Early/Late Heterobimetallics Support Unusual Trigonal Monopyramidal Geometries at both Zr and Co," Greenwood, B. P.; Rowe, G. T.; Chen, C.-H.; Foxman, B. M.; Thomas, C. M.  J. Am. Chem. Soc. 2010, 132, 44-45.
216.           "Hydrodefluorination and Other Hydrodehalogenation of Aliphatic Carbon−Halogen Bonds Using Silylium Catalysis," Douvris, C.; Nagaraja, C. M.; Chen, C.-H.; Foxman, B. M.; Ozerov, O. V. J. Am. Chem. Soc. 2010, 132, 4946-4953.
217.           "Hafnium alkyl complexes of the anionic PNP pincer ligand and possible alkylidene formation," Brammell, C. M.; Pelton, E. J.; Chen, C.-H.; Yakovenko, A. A.; Weng, W.; Foxman, B. M.; Ozerov, O. V. J. Organometal. Chem. 2011, 696, 4132-4137.
218.           "Structural Study-Guided Development of Versatile Phase-Transfer Catalysts for Asymmetric Conjugate Additions of Cyanide," Provencher, B. A.; Bartelson, K. J.; Liu, Y.; Foxman, B. M.; Deng, L. Angew. Chem., Int. Ed. 2011, 50, 10565-10569.
219.           "Subtle Differences Between Zr and Hf in Early/Late Heterobimetallic Complexes with Cobalt," Setty, V. N.; Zhou, W.; Foxman, B. M.; Thomas, C. M. Inorg. Chem. 2011, 50,  4647-4655.
220.           "Coordination of an N-Heterocyclic Phosphenium Containing Pincer Ligand to a Co(CO)2 Fragment Allows Oxidation To Form an Unusual N-Heterocyclic Phosphinito Species," Pan, B.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M. Organometallics 2011, 30, 5560-5563.
221.           "Activation of CO2 by a Heterobimetallic Zr/Co Complex," Krogman, J. P.; Foxman, B. M.; Thomas, C. M. J. Am. Chem. Soc. 2011, 133, 14582-14585.
222.           "Experimental and computational exploration of the dynamic behavior of (PNP)BF2, a boron compound supported by an amido/bis(phosphine) pincer ligand," DeMott, J. C.; Surawatanawong, P.; Barnett, S. M.; Chen, C.-H.; Foxman, B. M.; Ozerov, O. V. Dalton Trans. 2011, 40, 11562-11570.
223.           "Catalytic asymmetric [4 + 2] additions with aliphatic nitroalkenes," Bartelson, K. J.; Singh, R. P.; Foxman, B. M.; Deng , L. Chem. Sci. 2011, 2, 1940-1944.
224.           "Heterolytic Cleavage of B-H and B-B Bonds Across the N-Pd Bond in a Cationic (PNP)Pd Fragment," Zhu, Y.; Chen, C.-H.; Fafard, C.; Foxman, B. M.; Ozerov, O.V. Inorg. Chem. 2011, 50, 7980-7987.
225.           "Co-crystals of Isonicotinamide and p-Cyanobenzoic Acid," Dhal, A. K.; Chatterjee, S.; Sandman, D. J.; Chen, C.-H.; Foxman, B. M. J. Macromol. Sci., Chem. 2011, 48, 1038-1043.
226.           "Guilty as charged: non-innocent behavior by a pincer ligand featuring a central cationic phosphenium donor," Day, G. S.; Pan, B.; Kellenberger, D. L.; Foxman, B. M.; Thomas, C. M. Chem. Commun. 2011, 47, 3634-3636.
227.           "Stereospecific solid-state cyclodimerization of bis(trans-2-butenoato)calcium and triaquabis(trans-2-butenoato)magnesium," Hickey, M. B.; Schlam, R. F.; Guo, C.; Cho, T. H.; Snider, B. B.; Foxman, B. M. CrystEngComm  2011, 13, 3146-3155.
228.           "Chemo- and stereospecific solid-state dimerization of lithium trans-2-butenoate and lithium trans-2-butenoate formamide solvate," Shang, W.; Hickey, M. B.; Enkelmann, V.; Snider, B. B.; Foxman, B. M. CrystEngComm  2011, 13, 4339-4350.
229.           "Celecoxib sodium salt: engineering crystal forms for performance," Remenar, J. F.; Tawa, M. D.; Peterson, M. L.; Almarsson, Ö. Hickey, M. B.; Foxman, B. M. CrystEngComm  2011, 13, 1081-1089.
230.           "Reactivity of a Pd(I)−Pd(I) Dimer with O2: Monohapto Pd Superoxide and Dipalladium Peroxide in Equilibrium," Huacuja, R.; Graham, D. J.; Fafard, C. M.; Chen, C.-H.; Foxman, B. M.; Herbert, D. E.; Alliger, G.; Thomas, C. M.; Ozerov, O. V. J. Am. Chem. Soc. 2011, 133, 3280-3283.
231.           "N-Heterocyclic Phosphenium Ligands as Sterically and Electronically-Tunable Isolobal Analogues of Nitrosyls," Pan, B.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M. Inorg. Chem. 2012, 51, 4170-4179.
232.           "Heterolytic Activation of E-H Bonds Across Pt-P Bonds in Pt NHP (N-heterocyclic Phosphenium/Phosphido) Complexes," Pan, B.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M. Dalton Trans. 2012, 41, 9083-9090; DOI: 10.1039/C2DT30455D.
233.           "Synthesis and Structural Characterization of High Spin M/Cu (M = Mn, Fe) Heterobimetallic and Fe/Cu2 Trimetallic Phosphinoamides," Kuppuswamy, S.; Cooper, B. G.; Bezpalko, M. W.; Foxman, B. M.; Powers, T. M.; Thomas, C. M. Inorg. Chem. 2012, 51, 1866-1873.
234.           "Synthesis and Investigation of the Metal-Metal Interactions in Early/Late Heterobimetallic Complexes Linking Group 5 Imido Fragments to Co(I)," Evers, D. A.; Bluestein, A. H.; Foxman, B. M.; Thomas, C. M. Dalton Trans. 2012, 41, 8111-8115; DOI: 10.1039/C2DT00034B. 

235.           "Utilization of Phosphinoamide Ligands in Homobimetallic Fe and Mn Complexes: The Effect of Disparate Coordination Environments on Metal-Metal Interactions and Magnetic and Redox Properties," Kuppuswamy, S.;  Bezpalko, M. W.; Powers, T. M.; Turnbull, M. M.; Foxman, B. M.; Thomas, C. M.  Inorg. Chem. 2012, 51, 8225-8240.

236.           "Heterolytic addition of E-H bonds across Pt-P bonds in Pt N-heterocyclic phosphenium/phosphido complexes,"  Pan, B.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M. Dalton Trans. 2012, 41, 9083-9090; DOI: 10.1039/C2DT30455D.

237.           "Metal-Metal Interactions in C3-Symmetric Diiron Imido Complexes Linked by Phosphinoamide Ligands," Kuppuswamy, S.;  Powers, T. M.;  Johnson, B. M.;  Bezpalko, M. W.;  Brozek, C. K.; Foxman, B. M.;  Berben, L. A.; Thomas, C. M. Inorg. Chem. 2013, 52, 4802-4811; DOI: 10.1021/ic302108k.

238.           "Non-innocent Behavior of Bidentate Amidophosphido [NP]2- Ligands upon Coordination to Copper," Bezpalko , M. W. ; Foxman , B. M.; Thomas, C. M. Inorg. Chem. 2012, 52, 12329-12331; DOI: 10.1021/ic402257z.

239.           "Synthesis, Structure, and Reactivity of an Anionic Zr-Oxo Relevant to CO2 Reduction by a Zr/Co Heterobimetallic Complex," Krogman, J. P.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M.  Inorg. Chem. 2013, 52, 3022-3031; DOI: 10.1021/ic302473j.

240.           "Vanadium-iron complexes featuring metal-metal multiple bonds," Kuppuswamy, S.; Powers, T. M.; Krogman, J. P.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M. Chem. Sci. 2013, 4, 3557-3565; DOI: 10.1039/C3SC51337H.

241.           "Stoichiometric C═O Bond Oxidative Addition of Benzophenone by a Discrete Radical Intermediate To Form a Cobalt(I) Carbene," Marquard , S. L.; Bezpalko , M. W.; Foxman , B. M.; Thomas, C. M. J. Am. Chem. Soc. 2013, 135, 6018-6021; DOI: 10.1021/ja4022683.

242.           "Metal-Metal Bonding in Low-Coordinate Dicobalt Complexes Supported by Phosphinoamide Ligands," Mathialagan, R.; Kuppuswamy, S.; De Denko , A. T.; Bezpalko , M. W.; Foxman , B. M.; Thomas, C. M. Inorg. Chem. 2013, 52, 701-706.

243.           "Activation of E-H and E-E (E = S, O) Bonds by Heterobimetallic Zr/Co Complexes: Evidence for Both One- and Two-Electron Processes, "Napoline, J. W.; Krogman, J. P.; Shi, R.; Kuppuswamy, S.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M. Eur. J. Inorg. Chem. 2013, 3874-3882; DOI: 10.1002/ejic.201300122.

244.           "N-H activation of hydrazines by a heterobimetallic Zr-Co complex: promotion of one-electron chemistry at Zr," Napoline, J. W.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M. Chem. Commun. 2013, 49, 4388-4390; DOI: 10.1039/C2CC35594A.

245.           "Multimetallic Complexes Featuring a Bridging N-heterocyclic Phosphido/Phosphenium Ligand: Synthesis, Structure, and Theoretical Investigation," Pan ,B.; Evers-McGregor , D. A.; Bezpalko , M. W.; Foxman , B. M.; Thomas, C. M. Inorg. Chem. 2013, 52, 9583-9589; DOI: 10.1021/ic4012873.

246.           "Isolation of N-Heterocyclic Alkyl Intermediates en Route to Transition Metal N-Heterocyclic Carbene Complexes: Insight into a C-H Activation Mechanism," Pan, B.; Pierre, S.; Bezpalko, M. W.; Napoline, J. W.; Foxman, B. M.; Thomas, C. M. Organometallics 2013, 32, 704-710.

247.           "Crystallographic and magnetic studies of the 2-pyridone/copper halide system," Shortsleeves, K. C.; Turnbull, M. M.; Seith, C. B.; Tripodakis, E. N.; Xiao, F.; Landee, C. P.; Dawe, L. N.; Garrett, D.; de Delgado, G. D.; Foxman, B. M. Polyhedron 2013, 64, 110-121.

248.           "Understanding Pd-Pd Bond Length Variation in (PNP)Pd-Pd(PNP) Dimers," Walensky, J. R.; Fafard, C. M.; Guo, C.; Brammell, C. M.; Foxman, B. M.; Hall, M. B.; Ozerov, O. V. Inorg. Chem. 2013, 52, 2317-2322.

249.           "Active Cross-Linkers that Lead to Active Gels," Zhang, Y.; Zhou, N.; Akella, S.; Kuang, Y.; Kim, D.; Schwartz, A.; Bezpalko; M. W.; Foxman, B. M.; Fraden, S.; Epstein, I. R.; Xu, B.  Angew. Chem. Int. Ed. 2013, 52, 11494-11498; DOI: 10.1002/anie.201304437.

250.           "Catalytic Hydrosilylation of Ketones Using a Co/Zr Heterobimetallic Complex: Evidence for an Unusual Mechanism Involving Ketyl Radicals," Zhou, W.; Marquard, S. L.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M. Organometallics 2013, 32, 1766-1772; DOI: 10.1021/om301194g.

251.           "Palladium Complexes of a New Phosphine-Amido-Siloxide Pincer Ligand With Variable Degrees of Protonation,"Davidson, J. J.; Nagaraja, C. M.; Chen, C.-H.; Foxman, B. M.; Ozerov, O. V. Inorg. Chim. Acta 2014, 422, 70-77.

252.           "Fitting the Pieces of the Puzzle: The Delta Bond," Falvello, L. R.; Foxman, B. M.; Murillo, C. A. Inorg. Chem. 2014, 53, 9441−9456; DOI : 10.1021/ic500119h.

253.           My Life in Chemistry : More Fun Than Fun, Cotton, F. A.  Falvello, L. R.; Foxman, B. M., Murillo, C. A.; Murillo, D. Assoc. Eds. (*Professor Cotton was murdered in 2007. The associate editors helped bring the final work to publication.*). Elsevier, 2014.

254.           "Coordination of N-heterocyclic phosphine- and phosphenium-containing pincer ligands to copper(I): Evidence for reactive electrophilic metal-phosphenium intermediates," Knight, S. E.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M. Inorg. Chim. Acta  422, 2014, 181-187.

255.           "A series of C3-symmetric heterobimetallic Cr-M (M = Fe, Co and Cu) complexes," Kuppuswamy, S.; Bezpalko, M. W.; Powers, T. M.; Wilding, M. J. T.; Brozek, C. K.; Foxman, B. M.; Thomas, C. M. Chem. Sci. 2014, 5, 1617-1626 DOI: 10.1039/C3SC52943F.

256.           "Synthesis and Investigation of the Metal-Metal Interactions in Heterobimetallic Cr/Rh and Cr/Ir Complexes," Kuppuswamy, S.; Cass, T. R.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M. Inorg. Chim. Acta 2014, 424, 167-172.

257.           "One-Electron Oxidation Chemistry and Subsequent Reactivity of Diiron Imido Complexes," Kuppuswamy, S.; Powers, T. M.; Johnson, B. M.; Brozek, C. K.; Krogman, J. P.; Bezpalko, M. W.; Berben, L. A.; Keith, J.. M.; Foxman, B. M.; Thomas, C. M.  Inorg. Chem. 2014, 53, 5429-5437 DOI: 10.1021/ic403039x.

258.           "Interaction and Activation of Carbon-Heteroatom π-Bonds with a Zr/Co Heterobimetallic Complex," Marquard, S. L.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M. Organometallics 2014, 33, 2071-2079 DOI: 10.1021/om500217a.

259.           "Reduction of CO2 to Free CO by a Pd(I)-Pd(I) Dimer," Palita, C. M.; Graham, D. J.; Chen, C. H.; Foxman, B. M.; Ozerov, O. V. Chem. Commun. 2014, 50, 12840-12842; DOI: 10.1039/C4CC02438A.

260.           "Formation of Heterobimetallic Zirconium/Cobalt Diimido Complexes via a Four-Electron Transformation,"  Wu, B.; S´a;nchez, R. H.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M. Inorg. Chem. 2014, 53, 10021-10023; DOI: 10.1021/ic501490e.

261.           "Effect of ligand modification on the reactivity of phosphinoamide-bridged heterobimetallic Zr/Co complexes," Zhou, W.; Saper, N. I.; Krogman, J. P; Foxman, B. M.; Thomas, C. M. Dalton Trans. 2014, 43, 1984-1989 DOI: 10.1039/C3DT52133H.

262.           "Use of a Bidentate Ligand Featuring an N-Heterocyclic Phosphenium Cation (NHP+) to Systematically Explore the Bonding of NHP+ Ligands with Nickel," Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M.  Inorg. Chem. 2015, 54, 8717-8726; DOI: 10.1021/acs.organomet.5b00182.

263.           "Comparison of the Electronic Properties of Diarylamido-Based PNZ Pincer Ligands: Redox Activity at the Ligand and Donor Ability Toward the Metal," Davidson, J. J.; DeMott, J. C.; Douvris, C.; Fafard, C. M.; Bhuvanesh, N.; Chen, C.-H.;Herbert, D. E.; Lee, C.I.; McCulloch, B. J.; Foxman, B. M.; Ozerov, O. V. Inorg. Chem. 2015,  54,  2916-2935;  DOI: 10.1021/ic503062w.

264.           "Formation and Subsequent Reactivity of Heterobimetallic Zr/Co μ-oxo and Cobalt Hydride Complexes," Krogman, J. K.; Foxman, B. M.; Thomas, C. M. Organometallics 2015, 34, 3159-3166; DOI: 10.1021/acs.organomet.5b00182.

265.           "Probing substituent effects in phosphinoamine ligands using Mo(CO)5L Complexes," Lee, K. H.; Napoline, J. W.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M. Polyhedron 2015, 87, 354-360.

266.           "Experimental Establishment of Mother-Daughter Orientation Relationships and Twinning Effects in Phase Transitions : A Great Legacy from Jack Gougoutas and Peggy Etter," Posner, S. R.; Lorson, L. C.; Gell, A. R.; Foxman, B. M. Cryst. Growth Des. 2015, 15, 3407-3416; DOI: 10.1021/acs.cgd.5b00487.

267.           "Triflyloxy-substituted carboranes as useful weakly coordinating anions," Press, L. P.; McCulloch, B. J.; Gu, W.; Chen, C.-H.; Foxman, B. M.; Ozerov, O. V. Chem. Commun. 2015, 51, 14034-14037; DOI:10.1039/C5CC05047B.

268.           "A heterobimetallic complex featuring a Ti-Co multiple bond and its application to the reductive coupling of ketones to alkenes," Wu, B.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M. Chem. Sci. 2015, 6, 2044-2049; DOI: 10.1039/C4SC03772C.

269.           "Heterobimetallic Ti/Co Complexes That Promote Catalytic N-N Bond Cleavage," Wu, B.; Gramigna, K. M.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M. Inorg. Chem. 2015, 54, 10909-10917; DOI: 10.1021/acs.inorgchem.5b01962.

270.           "N-heterocyclic phosphenium and phosphido nickel complexes supported by a pincer ligand framework," Evers-McGregor, D. A.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M. Dalton Trans. 2016, 45, 1918-1929; DOI: 10.1039/C5DT03549J.

271.           "Multi-electron redox processes at a Zr(IV) center facilitated by an appended redox-active cobalt-containing metalloligand," Krogman, J. P.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M. Dalton Trans. 2016, 45, 11182-11190; DOI: 10.1039/C6DT01498D.

272.           "Lewis Acid Catalysis with Cationic Dinuclear Gold(II,II) and Gold(III,III) Phosphorus Ylide Complexes," Reiner, B. R.; Bezpalko, M. W.; Foxman, B. M.; Wade, C. R. Organometallics 2016, 35, 2830-2835; DOI: 10.1021/acs.organomet.6b00403.

273.           "Synthesis of chiral heterobimetallic tris(phosphinoamide) Zr/Co complexes," Saper, N. I.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M. Polyhedron 2016, 114, 88-95.

274.           "Exploring Trends in Metal-Metal Bonding, Spectroscopic Properties, and Conformational Flexibility in a Series of Heterobimetallic Ti/M and V/M Complexes (M = Fe, Co, Ni, and Cu)," Wu, B; Wilding, M. J. T.; Kuppuswamy, S.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M. Inorg. Chem. 2016, 55, 12137-12148; DOI: 10.1021/acs.inorgchem.6b01543.

275.           "An unprecedented case of dodecamorphism: the twelfth polymorph of aripiprazole formed by seeding with its active metabolite," Zeidan, T. A. ; Trotta, J. T.; Tilak, P. A.; Oliveira, M. A.; Chiarella, R. A.; Foxman, B. M.; Almarsson, Ö.; Hickey, M. B. CrystEngComm 2016, 18, 1486-1488 ; DOI: 10.1039/C5CE02467F.

276.           Bezpalko, M. W.; Poitras, A. M.; Foxman, B. M.; Thomas, C. M. "Cobalt N-Heterocyclic Phosphenium Complexes Stabilized by a Chelating Framework: Synthesis and Redox Properties," Inorg. Chem. 2016, 56, 503-510; DOI: 10.1021/acs.inorgchem.6b02374.

277.           "Exploring the coordination chemistry of N-heterocyclic phosphenium/phosphido ligands using nickelocene as a synthon,"  Evers-McGregor; D. A.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M. Inorg. Chim. Acta 2017, 460, 17-21; https://dx.doi.org/10.1016/ j.ica.2016.10.001.

278.           "Heterobimetallic Complexes Comprised of Nb and Fe: Isolation of a Coordinatively Unsaturated NbIII/Fe0 Bimetallic Complex Featuring a Nb≡Fe Triple Bond," , G.; , D. A.; , J. P; , M. J. T.; , M. W.; Foxman, B. M.; J. Am. Chem. Soc. 2017, 139, 9627-9636; DOI: 10.1021/jacs.7b04151

279.           "Electrochemical and structural investigation of the interactions between naphthalene diimides and metal cations," Reiner, B. R.; Foxman, B. M.; Wade, C. R.  Dalton Trans. 2017, 46, 9472-9480;  https://dx.doi.org/10.1039/C7DT02067H.

280.           "Investigation of Ketone C=O Bond Activation Processes by Heterobimetallic Zr/Co and Ti/Co Tris(Phosphinoamide) Complexes,"  Zhang, H.; Wu, B.; Marquard, S. L.; Litle, E. D.; Dickie, D. A.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M.  Organometallics, 2017, 36, 3498-3507, DOI: 10.1021/acs.organomet.7b00445.

281.           "Use of Topotactic Phase Transformations to Obtain Solutions of the Crystal Structures of Highly Disordered Materials," Lorson, L. C.; Tai, O.; Foxman, B. M.  Cryst. Growth Des. 2018, 18, 409-415; https://dx.doi.org/10.1021/acs.cgd.7b01406.

282.           "Zirconium Metal-Organic Frameworks Assembled from PNNNP Pd and Pt Pincer Complexes: Synthesis, Postsynthetic Modification, and Lewis Acid Catalysis," Reiner, B.; Mucha, N.; Rothstein, A.; Temme, S.; Duan, P.; Schmidt-Rohr, K.; Foxman, B. M.; Wade, C.  Inorg. Chem. 2018, 57, 2663-2672; DOI: 10.1021/acs.inorgchem.7b03063.

283.           "Addition of H2 Across a Cobalt-Phosphorus Bond." Poitras, A. M.; Knight, S. E.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M.  Angew. Chem. Int. Ed. 2018, 57, 1497-1500; DOI: 10.1002/anie.201710100.

284.           "New Look at Naltrexone Hydrochloride Hydrates: Understanding Phase Behavior and Characterization of Two Dihydrate Polymorphs," Steinberg, B. D.; Harris, E. T.; Foxman, B. M.; Oliveira, M. A.; Hickey. M. B. Cryst. Growth Des. 201818, 3502-3509; DOI: 10.1021/acs.cgd.8b00262.

285.           "Origin of and a Solution for Uneven Efficiency by Cinchona Alkaloid-Derived, Pseudoenantiomeric Catalysts for Asymmetric Reactions," , B.; , M. W.; , C.; , D. A.; , B. M.; J. Am. Chem. Soc. 2018, 140, 13913-13920; DOI: 10.1021/jacs.8b09010.

286.           "Absolute Configuration and Pharmacology of the Poison Frog Alkaloid Phantasmidine," , R. W.; ,B. B.; , Q.; , B. M.; , A. A.; , J. L.; , T. T.; , N.; , Y.; , K. D.; J. Nat. Prod. 2018, 81, 1029-1035, DOI: 10.1021/acs.jnatprod.8b0006.

287.           "Assessing the Metal-Metal Interactions in a Series of Heterobimetallic Nb/M Complexes (M = Fe, Co, Ni, Cu) and Their Effect on Multielectron Redox Properties," , B. A.; , G.;  , J. P.; , M. W.; , G. P.; , D. A.; , B. M.; Inorg. Chem. 2019, 58, 821-833; DOI: 10.1021/acs.inorgchem.8b02960.

288.           "O2 Activation by a Heterobimetallic Zr/Co Complex," , Zhang, H.; Moore, C. E.; Dickie, D. A.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M. J. Am. Chem. Soc. 2019, 141, 9516-9520;  DOI: 10.1021/jacs.9b04215. 

289.           "Cooperative H2 Activation across a Metal-Metal Multiple Bond and Hydrogenation Reactions Catalyzed by a Zr/Co Heterobimetallic Complex," Gramigna, K. M.; Dickie, D. A.; Foxman, B. M.; Thomas, C. M ACS Catalysis 20199, 3153-3164 DOI: 10.1021/acscatal.8b04390.

290.           "Cooperative activation of O-H and S-H bonds across the Co-P bond of an N-heterocyclic phosphido complex," Poitras, A. M.; Bezpalko, M. W.; Foxman, B. M.; Thomas, C. M. Dalton Trans., 2019, 48, 3074-3079; DOI:10.1039/C8DT05052J.

291.           "On the Crystal Structures of Missing Links in the Early History of Solid-State Reactions: The Group IA Acrylates and Methacrylates," Heyman, J. B.; Chen, C.-H.; Foxman, B. M. Cryst. Growth Des. 2020, 20, 330-336; DOI: 10.1021/acs.cgd.9b01267.

292.           "A Series of Dimeric Cobalt Complexes Bridged by N-Heterocyclic Phosphido Ligands," Poitras, A. M.; Bezpalko, M. W.; Moore, C. E.; Dickie, D. A.; Foxman, C. M.; Thomas, C. M. Inorg. Chem. 2020, 59, 4729-4740; DOI: 10.1021/acs.inorgchem.9b03790.

293.           "Dimerization of terminal alkynes promoted by a heterobimetallic Zr/Co complex,"  Beattie, J. W.; Wang, C.; Zhang, H.; Krogman, J. P.; Foxman, B. M.; Thomas, C. M. Dalton Trans., 2020, 49, 2407-2411; DOI: 10.1039/D0DT00334D.

294.           "Aripiprazole and Dehydro-Aripiprazole Solid Solutions: Crystalline Combinations of Drug and Active Metabolite in Tailored Compositions," Trotta, J. T.; Zeidan, T. A.; Tilak, P. A.; Foxman, B. M.; Almarsson, Ö.; Oliveira, M. A.; Chiarella, R. A.; Hickey, M. B.; Remenar, J. F. Cryst, Growth Des. 202020, 3944-3956; DOI: 10.1021/acs.cgd.0c00263.

295.           "Chemo- and Stereospecific Solid-State Thermal Dimerization of Sodium trans-2-Butenoate and γ-Ray-Induced Single-Crystal-to-Single-Crystal Dimerization of Hexaaquamag-nesium trans-2-Butenoate Dihydrate: Both Give rel-(3S,4R)-1-Hexene-3,4-dicarboxylate but by Different Mechanisms. Stereospecific γ-Ray-Induced Trimerization of Sodium trans-2-Butenoate," Shang, W.; Schlam, R. F.; Hickey, M. B.; Zhou, J.; Wheeler, K. A.; Diaz de Delgado, G. C.; Chen, C.-H.; Snider, B. B.; Foxman, B. M. Cryst. Growth Des. 2021; 21, 663-682; DOI: 10.1021/acs.cgd.0c01466.

296.           "Δ9-Tetrahydrocannabinolic acid A, the precursor to Δ9-tetrahydrocannabinol (THC)," Skell, J. M.; Kahn, M.; Foxman, B. M.  Acta Crystallogr. Sect. C: Struct. Chem. 2021, C77, 84-89; DOI: 10.1107/S2053229621000280.

297.          "cis-Copper(II)(L-DOPA-N,O)2 Monohydrate: Synthesis, Crystal Structure and Approaches to the Analysis of Pseudosymmetry," O'Brien, P.; Poyner, E. A.; Alraddadi, T. S.; Hursthouse, M. B.; Foxman, B. M.  Acta Crystallogr. Sect. C: Struct. Chem. 2021, C77, 383-390; DOI: 10.1107/S2053229621006082.  This paper was selected as the cover for the July 2021 issue.

298.          " Space Groups and Crystallographic Symmetry: Writing a Multi-featured Tutorial in a New Style," Foxman, B. M.  Acta Crystallogr. Sect. E: Crystallogr. Commun. 2021, E77, 857-863; DOI: 10.1107/S2056989021007039.  This paper was selected as the cover for the September 2021 issue.

___________________________________________________________________________________________________________________________________________________

Send content and research comments to Bruce Foxman (foxman1 at brandeis.edu)

Last updated 29 May 2021